bis(pentamethylcyclopentadienyl)dizinc

Base Information

• Chemical Name: bis(pentamethylcyclopentadienyl)dizinc
• CAS No.: 773895-85-5
• Molecular Formula: C₂₀H₃₀Zn₂
• Molecular Weight: 401.238
• Mol file: 773895-85-5.mol

Synonyms:

Chemical Property of bis(pentamethylcyclopentadienyl)dizinc

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(pentamethylcyclopentadienyl)dizinc

There total 2 articles about bis(pentamethylcyclopentadienyl)dizinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2C5(CH3)5(1-)*Zn(2+)=[(C5(CH3)5)2Zn] + diphenylzinc (1078-58-6) → bis(pentamethylcyclopentadienyl)dizinc (849926-75-6,773895-85-5) + (η5-C5Me5)Zn(C6H5)

Guidance literature:

In further solvent(s); equimolar solutions in (C2D5)2O mixed in an NMR tube at -20°C;

DOI:10.1002/anie.200462175

Reference yield:

(η1,η5)bis(pentamethylcyclopentadienyl)zinc (97286-54-9) + diphenylzinc (1078-58-6) → bis(pentamethylcyclopentadienyl)dizinc (849926-75-6,773895-85-5) + (η5-C5Me5)Zn(C6H5)

Guidance literature:

In diethyl ether; (Ar);

DOI:10.1021/ja0668217

Reference yield: 85.0%

bis(pentamethylcyclopentadienyl)dizinc (849926-75-6,773895-85-5) + C29H41N2(1-)*HMg(1+) → C39H56MgN2

Guidance literature:

In toluene; at -20 - 4 ℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/d1cc05617d

upstream raw materials:

diphenylzinc

(η1,η5)bis(pentamethylcyclopentadienyl)zinc

Downstream raw materials:

(η1,η5)bis(pentamethylcyclopentadienyl)zinc

zinc(II) iodide

bis(t-butoxy) zinc

zinc