Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)⁽¹⁺⁾*ClO₄^(1-)=[Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)]ClO₄

Base Information

• Chemical Name: Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)⁽¹⁺⁾*ClO₄^(1-)=[Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)]ClO₄
• CAS No.: 104730-82-7
• Molecular Formula: C₄₂H₃₆ClMnO₃P₃*ClO₄
• Molecular Weight: 871.509
• Mol file: 104730-82-7.mol

Synonyms:

Chemical Property of Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)⁽¹⁺⁾*ClO₄^(1-)=[Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)⁽¹⁺⁾*ClO₄^(1-)=[Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)]ClO₄

There total 2 articles about Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)⁽¹⁺⁾*ClO₄^(1-)=[Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)(1+)*ClO4(1-)=[Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)]ClO4 (104730-82-7,104760-44-3) → Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)(1+)*ClO4(1-)=[Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)]ClO4 (104730-82-7,104760-44-3)

Guidance literature:

In butan-1-ol; Ar-atmosphere; refluxing (7 h); solvent removal (vac.), dissoln. in CH2Cl2, filtration, concn., pptn. on Et2O addn.; elem. anal.;

DOI:10.1016/0022-328X(85)80418-6

Reference yield: 84.0%

fac-[Mn(OClO3)(CO)3(bis(diphenylphosphino)methane)] (78099-95-3) + (2-chloroethyl)diphenylphosphane (5055-11-8) → Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)(1+)*ClO4(1-)=[Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)]ClO4 (104730-82-7,104760-44-3)

Guidance literature:

In dichloromethane; Ar-atmosphere; refluxing (IR-monitoring); evapn. (vac.), washing (Et2O); elem. anal.;

DOI:10.1016/0022-328X(85)80418-6

Reference yield: 88.0%

Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)(1+)*ClO4(1-)=[Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)]ClO4 (104730-82-7,104760-44-3) → Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)(1+)*ClO4(1-)=[Mn(CO)3((C6H5)2PCH2P(C6H5)2)((C6H5)2PCH2CH2Cl)]ClO4 (104730-82-7,104760-44-3)

Guidance literature:

In butan-1-ol; Ar-atmosphere; refluxing (7 h); solvent removal (vac.), dissoln. in CH2Cl2, filtration, concn., pptn. on Et2O addn.; elem. anal.;

DOI:10.1016/0022-328X(85)80418-6

upstream raw materials:

fac-[Mn(OClO₃)(CO)3(bis(diphenylphosphino)methane)]

(2-chloroethyl)diphenylphosphane

Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)⁽¹⁺⁾*ClO₄^(1-)=[Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)]ClO₄

Downstream raw materials:

Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)⁽¹⁺⁾*ClO₄^(1-)=[Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)]ClO₄