[Rh(quinoline-κN)2(triphos-κ2P)](1+)

Base Information

• Chemical Name: [Rh(quinoline-κN)2(triphos-κ2P)](1+)
• CAS No.: 405072-76-6
• Molecular Formula: C₅₉H₅₃N₂P₃Rh
• Molecular Weight: 985.91
• Mol file: 405072-76-6.mol

Synonyms:

Chemical Property of [Rh(quinoline-κN)2(triphos-κ2P)](1+)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh(quinoline-κN)2(triphos-κ2P)](1+)

There total 3 articles about [Rh(quinoline-κN)2(triphos-κ2P)](1+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

quinoline (91-22-5) + (triphos)RhCl(C2H4) (105139-41-1) → [Rh(quinoline-κN)2(triphos-κ2P)](1+) (405072-76-6,405083-43-4,405083-95-6)

Guidance literature:

With thallium(I) hexafluorophosphate; In tetrahydrofuran-d8; r.t.; identified by NMR spectroscopy;

DOI:10.1002/1522-2675(20011017)84:10<2895::AID-HLCA2895>3.0.CO;2-0

Reference yield: 99.0%

quinoline (91-22-5) + [RhH(OSO2CF3)2(triphos)] → [Rh(quinoline-κN)2(triphos-κ2P)](1+) (405072-76-6,405083-43-4,405083-95-6)

Guidance literature:

In tetrahydrofuran-d8; r.t.; identified by NMR spectroscopy;

DOI:10.1002/1522-2675(20011017)84:10<2895::AID-HLCA2895>3.0.CO;2-0

Reference yield:

quinoline (91-22-5) + [(cyclooctadiene)Rh(κ3-1,1,1-tris(diphenylphosphanylmethyl)ethane)]PF6 (405072-86-8) → [Rh(quinoline-κN)2(triphos-κ2P)](1+) (405072-76-6,405083-43-4,405083-95-6)

Guidance literature:

In d⁽⁴⁾-methanol; heating to 100°C for 1 h; identified by NMR spectroscopy;

DOI:10.1002/1522-2675(20011017)84:10<2895::AID-HLCA2895>3.0.CO;2-0

upstream raw materials:

quinoline

[(cyclooctadiene)Rh(κ3-1,1,1-tris(diphenylphosphanylmethyl)ethane)]PF6

(triphos)RhCl(C₂H₄)

Downstream raw materials:

[Rh(H)2(quinoline-κN)(triphos-κ3P)]PF6

[Rh(quinoline-κN)2(triphos=O-κ2P)](1+)