[Rh(H)2(quinoline-κN)(triphos-κ3P)]PF6

Base Information

• Chemical Name: [Rh(H)2(quinoline-κN)(triphos-κ3P)]PF6
• CAS No.: 405072-79-9
• Molecular Formula: C₅₀H₄₈NP₃Rh*F₆P
• Molecular Weight: 1003.73
• Mol file: 405072-79-9.mol

Synonyms:

Chemical Property of [Rh(H)2(quinoline-κN)(triphos-κ3P)]PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh(H)2(quinoline-κN)(triphos-κ3P)]PF6

There total 2 articles about [Rh(H)2(quinoline-κN)(triphos-κ3P)]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

quinoline (91-22-5) + thallium(I) hexafluorophosphate (60969-19-9) + [RhCl(H)2(triphos)] (124154-37-6) → thallium chloride (55172-29-7,7791-12-0) + [Rh(H)2(quinoline-κN)(triphos-κ3P)]PF6 (405072-79-9)

Guidance literature:

In tetrahydrofuran; under N2 atm. to soln. (RhClH2(triphos)) and quinoline in THF was added TlPF6 and strirred for 1 h at r.t.; TlCl was filtered off, soln. was concd., heptane was added, ppt. was filtered off and washed with pentane; elem. anal.;

DOI:10.1002/1522-2675(20011017)84:10<2895::AID-HLCA2895>3.0.CO;2-0

Reference yield:

[Rh(quinoline-κN)2(triphos-κ2P)](1+) (405072-76-6,405083-43-4,405083-95-6) + hydrogen (1333-74-0) → [Rh(H)2(quinoline-κN)(triphos-κ3P)]PF6 (405072-79-9)

Guidance literature:

In tetrahydrofuran-d8; High Pressure; 30 bar H2, 40°C; identfied by NMR;

DOI:10.1002/1522-2675(20011017)84:10<2895::AID-HLCA2895>3.0.CO;2-0

upstream raw materials:

quinoline

thallium(I) hexafluorophosphate

[RhCl(H)2(triphos)]

[Rh(quinoline-κN)2(triphos-κ2P)](1+)