[Ru(bpm)3][Cl]2

Base Information

• Chemical Name: [Ru(bpm)3][Cl]2
• CAS No.: 65034-88-0
• Molecular Formula: C₂₄H₁₈N₁₂Ru*2Cl
• Molecular Weight: 646.463
• Mol file: 65034-88-0.mol

Synonyms:

Chemical Property of [Ru(bpm)3][Cl]2

Chemical Property:

• Melting Point: >300°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

[Ru(bpm)3][Cl]2 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(bpm)3][Cl]2

There total 3 articles about [Ru(bpm)3][Cl]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

dichlorotetrakis(dimethylsulfoxide)ruthenium(II) + 2,2'-Bipyrimidine (34671-83-5) → {Ru(bpm)3}Cl2 (65034-88-0)

Guidance literature:

In water; Ru(Me2SO)4Cl2 and bipyrimidine refluxed in water for 20h; mixt. filtered, evapd. to dryness, residue washed (acetone and cloroform), crude product was dissolved in water, filtered, slow addn. of EtOH and propanol (1:2) to the boiling filtrate, crystn. on cooling the soln., elem. anal.;

DOI:10.1016/S0277-5387(00)86759-5

Reference yield: 50.0%

ruthenium(III)chloride (10049-08-8,63767-78-2) + 2,2'-Bipyrimidine (34671-83-5) → {Ru(bpm)3}Cl2 (65034-88-0)

Guidance literature:

In melt; RuCl3 melted with ligand, reacted at 170°C for 4 h; extd. (CHCl3), recrystd. (MeOH);

DOI:10.1016/S0020-1693(00)86744-4

Reference yield:

ruthenium(III) chloride trihydrate (14898-67-0) + 2,2'-Bipyrimidine (34671-83-5) → {Ru(bpm)3}Cl2 (65034-88-0)

Guidance literature:

In ethylene glycol; Ru salt and bipyrimidine were refluxed and stirred in glycol for 1 h, soln. cooled, filtered and placed overnight in a freezer, red ppt. formed; ppt. sepd. and air dried; second crop was obtained by precipitating soln. with acetone and chromy.; elem. anal.;

upstream raw materials:

ruthenium(III) chloride trihydrate

2,2'-Bipyrimidine

ruthenium(III)chloride

Refernces

• 1、 Ross, Helen B.,Boldaji, Massoud,Rillema, D. Paul,Blanton, Charles B.,White, Russell P.. "Photosubstitution in tris chelate complexes of ruthenium(II) containing the ligands 2,2′-bipyrazine, 2,2′-bipyrimidine, 2,2′-bipyridine, and 4,4′-dimethyl-2,2′-bipyridine: Energy gap control". . p. 1013 - 1021. Retrieved 2008/10/08.