2-bromo-9,9-dimethyl-9,10-dihydroacridine

Base Information

• Chemical Name: 2-bromo-9,9-dimethyl-9,10-dihydroacridine
• CAS No.: 1443680-94-1
• Molecular Formula: C₁₅H₁₄BrN
• Molecular Weight: 288.187
• Mol file: 1443680-94-1.mol

Synonyms:

Chemical Property of 2-bromo-9,9-dimethyl-9,10-dihydroacridine

Chemical Property:

• Melting Point: 97 °C
• Boiling Point: 375.7±41.0 °C(Predicted)
• Density: 1.329±0.06 g/cm3(Predicted)

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-bromo-9,9-dimethyl-9,10-dihydroacridine

There total 9 articles about 2-bromo-9,9-dimethyl-9,10-dihydroacridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

9,9‐dimethyl‐10H‐acridine (6267-02-3) → 2-bromo-9,9-dimethyl-9,10-dihydroacridine (1443680-94-1)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide; for 12h; Cooling with ice; Darkness;

Reference yield: 80.0%

C15H16BrNO → 2-bromo-9,9-dimethyl-9,10-dihydroacridine (1443680-94-1)

Guidance literature:

With phosphoric acid;

Reference yield:

1,4-bromoiodobenzene (589-87-7) → 2-bromo-9,9-dimethyl-9,10-dihydroacridine (1443680-94-1)

Guidance literature:

Multi-step reaction with 3 steps

1: copper(l) iodide; potassium carbonate / 1,2-dichloro-benzene / 24 h / 180 °C

2: tetrahydrofuran / 0 - 20 °C / Inert atmosphere

3: phosphoric acid

With copper(l) iodide; phosphoric acid; potassium carbonate; In tetrahydrofuran; 1,2-dichloro-benzene;

upstream raw materials:

1,4-bromoiodobenzene

2-carbomethoxyaniline

2-(phenylamino)benzoic acid

Methyl N-phenylanthranilate

Downstream raw materials:

9,9-dimethyl-2-(9-phenyl-9H-carbazol-3-yl)-9,10-dihydroacridine

Refernces

• 1、 -. "Aromatic compound and organoelectroluminescent device comprising the compound". . . Retrieved 2021/08/31.
• 2、 -. "An electroluminescent compound and an electroluminescent device comprising the same". . . Retrieved 2020/09/26.