methyl cis-2,3-divinylcyclopropanecarboxylate

Base Information

• Chemical Name: methyl cis-2,3-divinylcyclopropanecarboxylate
• CAS No.: 853793-16-5
• Molecular Formula: C₉H₁₂O₂
• Molecular Weight: 152.193
• Mol file: 853793-16-5.mol

Synonyms:

Chemical Property of methyl cis-2,3-divinylcyclopropanecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl cis-2,3-divinylcyclopropanecarboxylate

There total 3 articles about methyl cis-2,3-divinylcyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vinylmagnesium chloride (3536-96-7) → methyl cis-2,3-divinylcyclopropanecarboxylate (853793-16-5) + 3-methoxycarbonyl-1,4-cycloheptadiene (65093-86-9)

Guidance literature:

vinylmagnesium chloride; (+/-)-[(1-methoxycarbonylpentadienyl)Fe(CO)3]PF₆; In tetrahydrofuran; dichloromethane; at -70 ℃; for 1h;

With ammonium cerium(IV) nitrate; In methanol; at 23 ℃; for 0.166667h; Title compound not separated from byproducts;

DOI:10.1021/ol050637t

Reference yield:

→ methyl cis-2,3-divinylcyclopropanecarboxylate (853793-16-5) + 3-methoxycarbonyl-1,4-cycloheptadiene (65093-86-9)

Guidance literature:

With ammonium cerium(IV) nitrate; In methanol; for 0.5h; Title compound not separated from byproducts.;

DOI:10.1055/s-2006-950312

Reference yield:

→ methyl cis-2,3-divinylcyclopropanecarboxylate (853793-16-5) + 3-methoxycarbonyl-1,4-cycloheptadiene (65093-86-9)

Guidance literature:

With ammonium cerium(IV) nitrate; In methanol; Title compound not separated from byproducts.;

DOI:10.1055/s-2006-950312

upstream raw materials:

vinylmagnesium chloride