2,2-dimethyl-4-(2-oxo-1,3-oxazolidin-5-yl)butyl(pyridine)bis(dimethylglyoximato(1-)-N,N')cobalt

Base Information

• Chemical Name: 2,2-dimethyl-4-(2-oxo-1,3-oxazolidin-5-yl)butyl(pyridine)bis(dimethylglyoximato(1-)-N,N')cobalt
• CAS No.: 333793-85-4
• Molecular Formula: C₂₂H₃₅CoN₆O₆
• Molecular Weight: 538.55
• Mol file: 333793-85-4.mol

Synonyms:

Chemical Property of 2,2-dimethyl-4-(2-oxo-1,3-oxazolidin-5-yl)butyl(pyridine)bis(dimethylglyoximato(1-)-N,N')cobalt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2-dimethyl-4-(2-oxo-1,3-oxazolidin-5-yl)butyl(pyridine)bis(dimethylglyoximato(1-)-N,N')cobalt

There total 1 articles about 2,2-dimethyl-4-(2-oxo-1,3-oxazolidin-5-yl)butyl(pyridine)bis(dimethylglyoximato(1-)-N,N')cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

bromo(pyridine)bis(dimethylglyoximato(1-)-N,N')cobalt + butane-2,3-dione dioxime (95-45-4) + 5-[3,3-Dimethyl-4-(trifluoromethylsulfonyloxy)butyl]-1,3-oxazolidin-2-one (333738-07-1) → 2,2-dimethyl-4-(2-oxo-1,3-oxazolidin-5-yl)butyl(pyridine)bis(dimethylglyoximato(1-)-N,N')cobalt (333793-85-4)

Guidance literature:

With sodium tetrahydroborate; In ethanol; light protection; mixt. of Co compd. and dimethylglyoxime in EtOH degassed and flushed with N2 for 1 h, suspn. of NaBH4 in EtOH added, stirred for 1 h, addn. of oxazolidin, stirred at room temp. for 12 h; extd. (CH2Cl2), combined extracts washed (water, brine), dried over K2CO3, solvent removed, chromy. (CH2Cl2/methanol/pyridine (95/2.5/0.1)), dried (high vac.);

DOI:10.1039/b004917o

upstream raw materials:

butane-2,3-dione dioxime

5-[3,3-Dimethyl-4-(trifluoromethylsulfonyloxy)butyl]-1,3-oxazolidin-2-one