Ethyl 2-bromo-2-methylcyclopropane-1-carboxylate

Base Information

Chemical Name:Ethyl 2-bromo-2-methylcyclopropane-1-carboxylate
CAS No.:89892-99-9
Molecular Formula:C7H11 Br O2
Molecular Weight:207.065
Hs Code.:
NSC Number:179426
DSSTox Substance ID:DTXSID50306721
Nikkaji Number:J1.753.475K

Synonyms:89892-99-9;ethyl 2-bromo-2-methylcyclopropane-1-carboxylate;NSC 179426;NSC179426;2-Bromo-2-methylcyclopropanecarboxylic acid ethyl ester;DTXSID50306721;MFCD11506673;NSC-179426;FT-0726235;ethyl 2-bromo-2-methylcyclopropane-carboxylate;A843370;ethyl 2-bromanyl-2-methyl-cyclopropane-1-carboxylate;2-bromo-2-methyl-1-cyclopropanecarboxylic acid ethyl ester;2-Bromo-2-methylcyclopropane-1-carboxylic acid ethyl ester

Suppliers and Price of Ethyl 2-bromo-2-methylcyclopropane-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of Ethyl 2-bromo-2-methylcyclopropane-1-carboxylate

Chemical Property:

Vapor Pressure:0.392mmHg at 25°C
Boiling Point:196.7°C at 760 mmHg
Flash Point:72.8°C
Density:1.477g/cm³
XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:205.99424
Heavy Atom Count:10
Complexity:158

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1CC1(C)Br

Technology Process of Ethyl 2-bromo-2-methylcyclopropane-1-carboxylate

There total 5 articles about Ethyl 2-bromo-2-methylcyclopropane-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 623-73-4
diazoacetic acid ethyl ester

: 557-93-7
2-bromoprop-1-ene

: 89892-99-9
2-bromo-2-methyl-cyclopropanecarboxylic acid ethyl ester

Guidance literature:: With dirhodium tetraacetate; at 20 ℃; for 56h; Inert atmosphere;
DOI:10.15227/orgsyn.085.0172

Reference yield: 50.0%

: 623-73-4
diazoacetic acid ethyl ester

: 557-93-7
2-bromoprop-1-ene

: 89892-99-9,136060-94-1,136060-95-2
ethyl trans-2-bromo-2-methylcyclopropanecarboxylate

Guidance literature:: With rhodium(II) acetate; at 20 ℃; Title compound not separated from byproducts;
DOI:10.1021/ja991908w

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 557-93-7
2-bromoprop-1-ene

: 89892-99-9,136060-94-1,136060-95-2
ethyl trans-2-bromo-2-methylcyclopropanecarboxylate

: 89892-99-9,136060-94-1,136060-95-2
ethyl cis-2-bromo-2-methylcyclopropanecarboxylate

Guidance literature:: With rhodium(II) acetate; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;
DOI:10.1021/ja00019a040