(+/-)-ptilocaulin

Base Information

Chemical Name:(+/-)-ptilocaulin
CAS No.:88154-76-1
Molecular Formula:C₁₅H₂₅N₃
Molecular Weight:247.384
Hs Code.:

Synonyms:

Suppliers and Price of (+/-)-ptilocaulin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (+/-)-ptilocaulin

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (+/-)-ptilocaulin

There total 11 articles about (+/-)-ptilocaulin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 53922-08-0,100692-90-8
1-methoxybicyclo<3.2.2>non-6-en-2-one

: 78777-02-3,86594-29-8,88154-76-1,88154-82-9,105930-25-4,105930-31-2,131100-65-7
(+/-)-ptilocaulin

Guidance literature:: Multi-step reaction with 10 steps

1: potassium tert-butoxide / tetrahydrofuran / 96 h / Ambient temperature

2: 87 percent / tetrahydrofuran; hexane / 1 h / -100 - -80 °C

3: 89 percent / TsOH / benzene / 1.5 h / 80 °C

4: 64 percent / benzene / 3 h / Irradiation

5: 1.) lithium tri-sec-butylborohydride, 2.) aq. sodium hydroxide, 30percent hydrogen peroxide / 1.) THF, RT, 12 h, 2.) RT, 2 h

6: 99 percent / imidazole / dimethylformamide / 14 h / Ambient temperature

7: 1.) borane-methyl sulfide, 2.) 3 M aq. NaOH, 30percent hydrogen peroxide / 1.) THF, 6 h, 0 deg C 2.) 50 deg C, 10 h

8: 97 percent / Collins reagent / CH₂Cl₂ / 0.08 h / Ambient temperature

9: potassium tert-butoxide / tetrahydrofuran; 2-methyl-propan-2-ol / 0.5 h / Ambient temperature

10: benzene / 25 h / Heating

With 1H-imidazole; sodium hydroxide; dimethylsulfide borane complex; Collins oxidation agent; potassium tert-butylate; dihydrogen peroxide; L-Selectride; toluene-4-sulfonic acid; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol; benzene;
DOI:10.1021/jo00251a004

Reference yield:

: 103931-12-0
1-butyl-exo-8-methylbicyclo<3.2.2>non-6-en-2-one

: 78777-02-3,86594-29-8,88154-76-1,88154-82-9,105930-25-4,105930-31-2,131100-65-7
(+/-)-ptilocaulin

Guidance literature:: Multi-step reaction with 7 steps

1: 64 percent / benzene / 3 h / Irradiation

2: 1.) lithium tri-sec-butylborohydride, 2.) aq. sodium hydroxide, 30percent hydrogen peroxide / 1.) THF, RT, 12 h, 2.) RT, 2 h

3: 99 percent / imidazole / dimethylformamide / 14 h / Ambient temperature

4: 1.) borane-methyl sulfide, 2.) 3 M aq. NaOH, 30percent hydrogen peroxide / 1.) THF, 6 h, 0 deg C 2.) 50 deg C, 10 h

5: 97 percent / Collins reagent / CH₂Cl₂ / 0.08 h / Ambient temperature

6: potassium tert-butoxide / tetrahydrofuran; 2-methyl-propan-2-ol / 0.5 h / Ambient temperature

7: benzene / 25 h / Heating

With 1H-imidazole; sodium hydroxide; dimethylsulfide borane complex; Collins oxidation agent; potassium tert-butylate; dihydrogen peroxide; L-Selectride; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol; benzene;
DOI:10.1021/jo00251a004

Reference yield:

: 103931-13-1
4-butyl-exo-3-methylbicyclo<4.3.0>non-4-en-7-one

: 78777-02-3,86594-29-8,88154-76-1,88154-82-9,105930-25-4,105930-31-2,131100-65-7
(+/-)-ptilocaulin

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) lithium tri-sec-butylborohydride, 2.) aq. sodium hydroxide, 30percent hydrogen peroxide / 1.) THF, RT, 12 h, 2.) RT, 2 h

2: 99 percent / imidazole / dimethylformamide / 14 h / Ambient temperature

3: 1.) borane-methyl sulfide, 2.) 3 M aq. NaOH, 30percent hydrogen peroxide / 1.) THF, 6 h, 0 deg C 2.) 50 deg C, 10 h

4: 97 percent / Collins reagent / CH₂Cl₂ / 0.08 h / Ambient temperature

5: potassium tert-butoxide / tetrahydrofuran; 2-methyl-propan-2-ol / 0.5 h / Ambient temperature

6: benzene / 25 h / Heating

With 1H-imidazole; sodium hydroxide; dimethylsulfide borane complex; Collins oxidation agent; potassium tert-butylate; dihydrogen peroxide; L-Selectride; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; tert-butyl alcohol; benzene;
DOI:10.1021/jo00251a004