kibdelone C methyl ether

Base Information

Chemical Name:kibdelone C methyl ether
CAS No.:1311379-39-1
Molecular Formula:C₃₀H₃₀ClNO₁₀
Molecular Weight:600.022
Hs Code.:

Synonyms:

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Chemical Property of kibdelone C methyl ether

Chemical Property:

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Technology Process of kibdelone C methyl ether

There total 15 articles about kibdelone C methyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₇H₂₀O₄

: 934464-79-6
kibdelone C

: 1311379-39-1
kibdelone C methyl ether

Guidance literature:: Multi-step reaction with 12 steps

1: sodium chlorite; sodium phosphate monobasic monohydrate / 2-methyl-but-2-ene; water; tert-butyl alcohol / 0 °C

2: sulfuric acid / 0 - 20 °C / Inert atmosphere

3: toluene-4-sulfonic acid / tetrahydrofuran / 80 °C / Inert atmosphere

4: chloro-trimethyl-silane; sodium cyanoborohydride / acetonitrile / 0 °C / Inert atmosphere; Heating

5: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 3 h / 80 °C / Inert atmosphere

6: magnesium iodide / dichloromethane / -78 - -20 °C / Inert atmosphere

7: boron trichloride / dichloromethane / 1 h / -78 °C / Inert atmosphere

8: 10-camphorsufonic acid / dichloromethane / 1 h / 40 °C / Inert atmosphere; Sonication

9: potassium phosphate / dimethyl sulfoxide / 50 °C / Inert atmosphere

10: lithium hydroxide monohydrate; water / 1,4-dioxane / 75 °C / Inert atmosphere

11: pyridine; 1,3,5-trichloro-2,4,6-triazine / 1,2-dichloro-ethane / 1.08 h / 20 - 75 °C / Inert atmosphere

12: CAN adsorbed on silica gel / dichloromethane / Inert atmosphere

With pyridine; sodium chlorite; potassium phosphate; chloro-trimethyl-silane; 1,3,5-trichloro-2,4,6-triazine; sodium phosphate monobasic monohydrate; lithium hydroxide monohydrate; sulfuric acid; 10-camphorsufonic acid; water; boron trichloride; sodium cyanoborohydride; toluene-4-sulfonic acid; magnesium iodide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; 1,4-dioxane; 2-methyl-but-2-ene; dichloromethane; water; dimethyl sulfoxide; ethyl acetate; 1,2-dichloro-ethane; acetonitrile; tert-butyl alcohol; 1: Pinnick oxidation / 6: intramolecular halo-Michael aldol reaction;
DOI:10.1021/ja203642n

Reference yield:

: C₁₇H₂₀O₅

: 934464-79-6
kibdelone C

: 1311379-39-1
kibdelone C methyl ether

Guidance literature:: Multi-step reaction with 11 steps

1: sulfuric acid / 0 - 20 °C / Inert atmosphere

2: toluene-4-sulfonic acid / tetrahydrofuran / 80 °C / Inert atmosphere

3: chloro-trimethyl-silane; sodium cyanoborohydride / acetonitrile / 0 °C / Inert atmosphere; Heating

4: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 3 h / 80 °C / Inert atmosphere

5: magnesium iodide / dichloromethane / -78 - -20 °C / Inert atmosphere

6: boron trichloride / dichloromethane / 1 h / -78 °C / Inert atmosphere

7: 10-camphorsufonic acid / dichloromethane / 1 h / 40 °C / Inert atmosphere; Sonication

8: potassium phosphate / dimethyl sulfoxide / 50 °C / Inert atmosphere

9: lithium hydroxide monohydrate; water / 1,4-dioxane / 75 °C / Inert atmosphere

10: pyridine; 1,3,5-trichloro-2,4,6-triazine / 1,2-dichloro-ethane / 1.08 h / 20 - 75 °C / Inert atmosphere

11: CAN adsorbed on silica gel / dichloromethane / Inert atmosphere

With pyridine; potassium phosphate; chloro-trimethyl-silane; 1,3,5-trichloro-2,4,6-triazine; lithium hydroxide monohydrate; sulfuric acid; 10-camphorsufonic acid; water; boron trichloride; sodium cyanoborohydride; toluene-4-sulfonic acid; magnesium iodide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; 1,4-dioxane; dichloromethane; dimethyl sulfoxide; ethyl acetate; 1,2-dichloro-ethane; acetonitrile; 5: intramolecular halo-Michael aldol reaction;
DOI:10.1021/ja203642n

Reference yield:

: 1311379-26-6
C₁₅H₁₈O₅

: 934464-79-6
kibdelone C

: 1311379-39-1
kibdelone C methyl ether

Guidance literature:: Multi-step reaction with 10 steps

1: toluene-4-sulfonic acid / tetrahydrofuran / 80 °C / Inert atmosphere

2: chloro-trimethyl-silane; sodium cyanoborohydride / acetonitrile / 0 °C / Inert atmosphere; Heating

3: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 3 h / 80 °C / Inert atmosphere

4: magnesium iodide / dichloromethane / -78 - -20 °C / Inert atmosphere

5: boron trichloride / dichloromethane / 1 h / -78 °C / Inert atmosphere

6: 10-camphorsufonic acid / dichloromethane / 1 h / 40 °C / Inert atmosphere; Sonication

7: potassium phosphate / dimethyl sulfoxide / 50 °C / Inert atmosphere

8: lithium hydroxide monohydrate; water / 1,4-dioxane / 75 °C / Inert atmosphere

9: pyridine; 1,3,5-trichloro-2,4,6-triazine / 1,2-dichloro-ethane / 1.08 h / 20 - 75 °C / Inert atmosphere

10: CAN adsorbed on silica gel / dichloromethane / Inert atmosphere

With pyridine; potassium phosphate; chloro-trimethyl-silane; 1,3,5-trichloro-2,4,6-triazine; lithium hydroxide monohydrate; 10-camphorsufonic acid; water; boron trichloride; sodium cyanoborohydride; toluene-4-sulfonic acid; magnesium iodide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; 1,4-dioxane; dichloromethane; dimethyl sulfoxide; ethyl acetate; 1,2-dichloro-ethane; acetonitrile; 4: intramolecular halo-Michael aldol reaction;
DOI:10.1021/ja203642n