cis-Ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)oxalatoplatinum

Base Information

• Chemical Name: cis-Ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)oxalatoplatinum
• CAS No.: 325139-43-3
• Molecular Formula: C₁₁H₂₂N₃O₅Pt
• Molecular Weight: 471.393
• DSSTox Substance ID: DTXSID301036233
• Mol file: 325139-43-3.mol

Synonyms:DTXSID301036233;cis-Ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)oxalatoplatinum;325139-43-3

Chemical Property of cis-Ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)oxalatoplatinum

Chemical Property:

• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 472.128565
• Heavy Atom Count: 20
• Complexity: 220

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1(CC(CC(N1O)(C)C)N)C.C(=O)(C(=O)[O-])[O-].N.[Pt+2]

Technology Process of cis-Ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)oxalatoplatinum

There total 1 articles about cis-Ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)oxalatoplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II) (325148-41-2,170309-76-9) + potassium oxalate monohydrate (6487-48-5) → cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)oxalatoplatinum (II) (325139-43-3)

Guidance literature:

With AgNO₃; In water; AgNO3 was added with stirring to soln. of Pt complex; mixt. was stirred for 12 h in the dark; ppt. of silver halides was removed by centrifugation to give an orange soln.; soln. of oxalate was added; mixt. was allowed to stand for 12 h at 10°C; concd.; crystals filtered off, washed with cold water and EtOH, dried invacuo; recrystn. from water; elem. anal.;

DOI:10.1007/BF02495168

upstream raw materials:

cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II)

potassium oxalate monohydrate