cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II)

Base Information

• Chemical Name: cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II)
• CAS No.: 325148-41-2
• Molecular Formula: C₉H₂₂ClIN₃OPt
• Molecular Weight: 545.731
• Mol file: 325148-41-2.mol

Synonyms:

Chemical Property of cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II)

There total 2 articles about cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

Na(1+)*[Pt(NH3)Cl3](1-)=Na[Pt(NH3)Cl3] (101151-57-9) + 4-amino-2,2,6,6-tetramethyl-1-piperidine-1-oxyl (14691-88-4,78774-22-8) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II) (325148-41-2,170309-76-9)

Guidance literature:

In water; aq. solns. of NaI and the amine were added at ca. 20°C to a stirred aq. soln. of Pt complex; resulting suspn. was stirred for 2 h; ppt. filtered off, washed with cold H2O and dried in air;

DOI:10.1007/BF02495168

Reference yield: 42.0%

P(C6H5)4(1+)*Pt(NH3)(Cl)3(1-) = [P(C6H5)4][Pt(NH3)(Cl)3] (110790-59-5) + sodium tetraphenyl borate (143-66-8) + 4-amino-2,2,6,6-tetramethyl-1-piperidine-1-oxyl (14691-88-4,78774-22-8) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II) (325148-41-2,170309-76-9)

Guidance literature:

In methanol; water; mixing; crystn. (6 h, 23°C, dark), filtn., washing (water, MeOH); elem. anal.;

DOI:10.1021/ja00148a012

Reference yield: 71.0%

cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)iodochloroplatinum (II) (325148-41-2,170309-76-9) + potassium chloride → cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)dichloroplatinum (II) (170309-75-8)

Guidance literature:

With AgNO₃; In water; AgNO3 was added with stirring to soln. of Pt complex; mixt. was stirred for 12 h in the dark; ppt. of silver halides was removed by centrifugation to give an orange soln.; soln. of KCl was added; mixt. was allowed tostand for 12 h at ca. 20°C; concd.; crystals filtered off, washed with cold water and EtOH, dried invacuo; recrystn. from EtOH; elem. anal.;

DOI:10.1007/BF02495168

upstream raw materials:

Na⁽¹⁺⁾*[Pt(NH₃)Cl₃]^(1-)=Na[Pt(NH₃)Cl₃]

4-amino-2,2,6,6-tetramethyl-1-piperidine-1-oxyl

sodium iodide

P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]

Downstream raw materials:

cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)dichloroplatinum (II)

cis-ammine(4-amino-2,2,6,6-tetramethylpiperidin-1-oxyl)oxalatoplatinum (II)

Pt(NH₃)(NH₂C₅H₅(CH₃)4NO)((C₅H₂N₄ONH₂C₄H₅O(OH)CH₂)2PO₄)⁽¹⁺⁾

Pt(NH₃)(NH₂C₅H₅(CH₃)4NO)((C₅H₂N₄ONH₂C₄H₅O(OH)CH₂)2PO₄)⁽¹⁺⁾