3-Methyl-2-butanone 2,4-dinitrophenyl hydrazone

Base Information

• Chemical Name: 3-Methyl-2-butanone 2,4-dinitrophenyl hydrazone
• CAS No.: 3077-97-2
• Molecular Formula: C11H14 N4 O4
• Molecular Weight: 266.257
• Hs Code.: 2928000090
• NSC Number: 171195
• Nikkaji Number: J130.780K
• Mol file: 3077-97-2.mol

Synonyms:3077-97-2;3-Methyl-2-butanone 2,4-dinitrophenylhydrazone;NSC171195;NSC-171195;3-Methyl-2-butanone 2,4-dinitrophenyl hydrazone

Chemical Property of 3-Methyl-2-butanone 2,4-dinitrophenyl hydrazone

Chemical Property:

• Vapor Pressure: 3.29E-06mmHg at 25°C
• Boiling Point: 387.4 °C at 760 mmHg
• Flash Point: 188.1 °C
• PSA: 116.03000
• Density: 1.33 g/cm³
• LogP: 4.06620
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 266.10150494
• Heavy Atom Count: 19
• Complexity: 372

Purity/Quality:

99% ^*data from raw suppliers

METHYL ISOPROPYL KETONE-DNPH 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C(=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])C
• Isomeric SMILES: CC(C)/C(=N\NC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])/C

Technology Process of 3-Methyl-2-butanone 2,4-dinitrophenyl hydrazone

There total 8 articles about 3-Methyl-2-butanone 2,4-dinitrophenyl hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-Methyl-3-buten-2-one (814-78-8,25988-32-3) → 3-methyl-2-butanone (2,4-dinitrophenyl)hydrazone (3077-97-2)

Guidance literature:

Multi-step reaction with 2 steps

1: Raney nickel; ethanol / 20 - 32 °C / Hydrogenation_.unter Druck

With ethanol; nickel;

Reference yield:

3-Hydroxy-3-methyl-2-butanone (115-22-0) → 3-methyl-2-butanone (2,4-dinitrophenyl)hydrazone (3077-97-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 485 °C / Pyrolysis_.Reaktion des Essigsaeureesters

2: Raney nickel; ethanol / 20 - 32 °C / Hydrogenation_.unter Druck

With ethanol; nickel;

Reference yield:

2-methylbut-1-en-3-yne (78-80-8) → 3-methyl-2-butanone (2,4-dinitrophenyl)hydrazone (3077-97-2)

Guidance literature:

Multi-step reaction with 3 steps

1: mercury (II)-acetate; acetic acid / 75 - 85 °C

2: Raney nickel; ethanol / 20 - 32 °C / Hydrogenation_.unter Druck

With ethanol; mercury(II) diacetate; nickel; acetic acid;

upstream raw materials:

trimethyloxirane

(2,4-dinitro-phenyl)-hydrazine

3-methyl-butan-2-one

3-methyl-2-butanol

Refernces

• 1、 Mathur, Dwarka, L.,Agarwal, Anupma,Banerji, Kalyan K.. "Kinetics and Mechanism of Oxidation of Alcohols by Ceric Ammonium Nitrate". . p. 519 - 522. Retrieved 2007/10/02.