4-[4-(Methoxycarbonyl)phenylethynyl]benzeneboronic acid pinacol ester, 95%

Base Information

• Chemical Name: 4-[4-(Methoxycarbonyl)phenylethynyl]benzeneboronic acid pinacol ester, 95%
• CAS No.: 1448637-05-5
• Molecular Formula: C₂₂H₂₃BO₄
• Molecular Weight: 362.233
• Mol file: 1448637-05-5.mol

Synonyms:

Chemical Property of 4-[4-(Methoxycarbonyl)phenylethynyl]benzeneboronic acid pinacol ester, 95%

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

4-[4-(4,4,5,5-Tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenylethynyl]benzoicAcidMethylEster ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-[4-(Methoxycarbonyl)phenylethynyl]benzeneboronic acid pinacol ester, 95%

There total 1 articles about 4-[4-(Methoxycarbonyl)phenylethynyl]benzeneboronic acid pinacol ester, 95% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

C16H11BrO2 (2365379-82-2) + bis(pinacol)diborane (73183-34-3) → methyl 4-((4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)ethynyl)benzoate (1448637-05-5)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium acetate; palladium diacetate; In 1,4-dioxane; at 80 ℃;

DOI:10.1021/jacs.9b06445

upstream raw materials:

C₁₆H₁₁BrO₂

bis(pinacol)diborane

Refernces

• 1、 Chen, Zhijie,Li, Penghao,Wang, Xingjie,Otake, Ken-Ichi,Zhang, Xuan,Robison, Lee,Atilgan, Ahmet,Islamoglu, Timur,Hall, Morgan G.,Peterson, Gregory W.,Stoddart, J. Fraser,Farha, Omar K.. "Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks". supporting information. p. 12229 - 12235. Retrieved 2019/08/27.