Methyl 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-3-carboxylate

Base Information

• Chemical Name: Methyl 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-3-carboxylate
• CAS No.: 1256358-85-6
• Molecular Formula: C₂₀H₂₃BO₄
• Molecular Weight: 338.211
• Hs Code.: 2931900090
• European Community (EC) Number: 804-972-4
• DSSTox Substance ID: DTXSID00681914
• Wikidata: Q82606094
• Mol file: 1256358-85-6.mol

Synonyms:1256358-85-6;Methyl 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-3-carboxylate;3'-(Methoxycarbonyl)biphenyl-4-boronic acid pinacol ester;methyl 3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]benzoate;3/'-(Methoxycarbonyl)biphenyl-4-boronic acid pinacol ester, 95per cent;DTXSID00681914;WHJJVEIJHJEWDK-UHFFFAOYSA-N;MFCD16294535;AKOS016339746;AS-2641;CS-0153862;A920139;Methyl [1,1'-biphenyl]-3-carboxylate-4'-boronic acid pinacol ester;Methyl 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)[1,1'-biphenyl]-3-carboxylate;Methyl4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-3-carboxylate;[1,1'-Biphenyl]-3-carboxylic acid, 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-, methyl ester

Chemical Property of Methyl 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-3-carboxylate

Chemical Property:

• Boiling Point: 465.9±38.0 °C(Predicted)
• Density: 1.12±0.1 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 338.1689394
• Heavy Atom Count: 25
• Complexity: 466

Purity/Quality:

97% ^*data from raw suppliers

Methyl 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-3-carboxylate >95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: B1(OC(C(O1)(C)C)(C)C)C2=CC=C(C=C2)C3=CC(=CC=C3)C(=O)OC
• Uses: 3''-(Methoxycarbonyl)biphenyl-4-boronic acid pinacol ester

Technology Process of Methyl 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-3-carboxylate

There total 2 articles about Methyl 4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-3-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(pinacol)diborane (73183-34-3) + methyl 3-(4'-N,N-dimethylaminophenyl)benzoate → C20H23BO4 (1256358-85-6)

Guidance literature:

With pyrene; carbon dioxide; at 30 ℃; for 24h; under 760.051 Torr; UV-irradiation;

DOI:10.1021/acs.orglett.1c01503

Reference yield:

[3-(methoxycarbonyl)phenyl]boronic acid (99769-19-4) → C20H23BO4 (1256358-85-6)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium phosphate / methanol; water / Reflux; Inert atmosphere

2: pyrene; carbon dioxide / 24 h / 30 °C / 760.05 Torr / UV-irradiation

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; pyrene; carbon dioxide; In methanol; water;

DOI:10.1021/acs.orglett.1c01503

upstream raw materials:

[3-(methoxycarbonyl)phenyl]boronic acid

bis(pinacol)diborane

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1256358-85-6 3'-(Methoxycarbonyl)biphenyl-4-boronic acid pinacol ester, 95%

Send

Send

Metric Ton KG G Pound L ML

Send

Send