1-O-formyl-2,3,5-tri-O-methyl-D-arabinose methyl hemiacetal

Base Information

• Chemical Name: 1-O-formyl-2,3,5-tri-O-methyl-D-arabinose methyl hemiacetal
• CAS No.: 74720-59-5
• Molecular Formula: C₁₀H₂₀O₇
• Molecular Weight: 252.265
• Mol file: 74720-59-5.mol

Synonyms:

Chemical Property of 1-O-formyl-2,3,5-tri-O-methyl-D-arabinose methyl hemiacetal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-O-formyl-2,3,5-tri-O-methyl-D-arabinose methyl hemiacetal

There total 2 articles about 1-O-formyl-2,3,5-tri-O-methyl-D-arabinose methyl hemiacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.7%

2,3,4,6-tetra-O-methyl-D-glucose (3615-47-2) → O-(2,4-di-O-methyl-D-erythrose)-(1<*>2)-3-O-methyl-D-glyceraldehyde (74720-58-4) + 1-O-formyl-2,3,5-tri-O-methyl-D-arabinose methyl hemiacetal (74720-59-5) + O-(2,4-di-O-methyl-D-erythrose)-(1<*>3)-2,4-di-O-methyl-D-erythronic acid (74720-61-9) + methyl 2,3,5-tri-O-methyl-D-arabinoside (34338-82-4) + 2,3,5-tri-O-methyl-D-arabinonolactone (74720-60-8) + 2,3,4,6-tetra-O-methyl-D-glucono-1,5-lactone (35510-38-4)

Guidance literature:

With potassium hydroxide; dihydrogen peroxide; In water; at 25 ℃; for 43h; Product distribution; various temp., times, reagents;

DOI:10.1016/S0008-6215(00)85701-8

Reference yield: 4.0%

2,3,4,6-tetra-O-methyl-D-glucose (3615-47-2) → 1-O-formyl-2,3,5-tri-O-methyl-D-arabinose methyl hemiacetal (74720-59-5) + methyl 2,3,5-tri-O-methyl-D-arabinoside (34338-82-4) + 2,3,5-tri-O-methyl-D-arabinonolactone (74720-60-8) + 2,3,4,6-tetra-O-methyl-D-glucono-1,5-lactone (35510-38-4)

Guidance literature:

With potassium hydroxide; dihydrogen peroxide; In water; at 25 ℃; for 43h; Further byproducts given;

DOI:10.1016/S0008-6215(00)85701-8

upstream raw materials:

2,3,4,6-tetra-O-methyl-D-glucose