FCF=CFFe(CO)2Cp

Base Information

Chemical Name:FCF=CFFe(CO)2Cp
CAS No.:12152-59-9
Molecular Formula:C₉H₅F₃FeO₂
Molecular Weight:257.98
Hs Code.:

Synonyms:

Suppliers and Price of FCF=CFFe(CO)2Cp

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Chemical Property of FCF=CFFe(CO)2Cp

Chemical Property:

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Technology Process of FCF=CFFe(CO)2Cp

There total 4 articles about FCF=CFFe(CO)2Cp which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: potassium cyclopentadienyldicarbonyliron⁽⁰⁾

: 598-73-2,55157-25-0
1-bromo-1,2,2-trifluoroethene

: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

: dicarbonylcyclopentadienylbromoiron(II)

: 12152-59-9
FCF=CFFe(CO)2Cp

Guidance literature:: In tetrahydrofuran; under Ar; alkenyl halide mixed with FpK soln. pre-cooled at -50 °C; after 10-15 min react. mixt. allowed to reach room temp.; not isolated; NMR;
DOI:10.1016/S0022-328X(03)00531-X

Reference yield: 5.0%

: potassium cyclopentadienyldicarbonyliron⁽⁰⁾

: 598-73-2,55157-25-0
1-bromo-1,2,2-trifluoroethene

: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

: 12152-59-9
FCF=CFFe(CO)2Cp

Guidance literature:: With t-butyl alcohol; In tetrahydrofuran; byproducts: CF2=CFH, t-BuOCF2CFHBr; under Ar; react. in the presence of t-BuOH; alkenyl halide mixed with FpK soln. pre-cooled at -50 °C; after 10-15 min react. mixt. allowed to reach room temp.; not isolated; NMR;
DOI:10.1016/S0022-328X(03)00531-X

Reference yield:

: potassium cyclopentadienyldicarbonyliron⁽⁰⁾

: 79-38-9,9036-80-0
Chlorotrifluoroethylene

: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

: 12152-59-9
FCF=CFFe(CO)2Cp

: 894773-07-0
[(C₅H₅)Fe(CO)2CF₂CHFCl]

Guidance literature:: With t-BuOH; LiCl; In tetrahydrofuran; byproducts: KCl, CF2=CFH; soln. of Fe complex in THF was stirred with LiCl in THF; t-BuOH was added; mixt. was cooled to -50°C; soln. of alkene in THF was introduced; reacted at -50°C for 15 min; warmed to room temp.; sublimed (30-50°C, 0.05 Torr, 2 h); crystd. (petroleum ether, 20 to -80°C);
DOI:10.1016/j.jorganchem.2005.12.050