Phosphinic chloride, phenyl(1-phenylethyl)-

Base Information

Chemical Name:Phosphinic chloride, phenyl(1-phenylethyl)-
CAS No.:140458-23-7
Molecular Formula:C14H14ClOP
Molecular Weight:264.691
Hs Code.:
DSSTox Substance ID:DTXSID70438992
Mol file:140458-23-7.mol

Synonyms:Phosphinic chloride, phenyl(1-phenylethyl)-;140458-23-7;DTXSID70438992

Suppliers and Price of Phosphinic chloride, phenyl(1-phenylethyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Phosphinic chloride, phenyl(1-phenylethyl)-

Chemical Property:

XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:264.0470798
Heavy Atom Count:17
Complexity:280

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C1=CC=CC=C1)P(=O)(C2=CC=CC=C2)Cl

Technology Process of Phosphinic chloride, phenyl(1-phenylethyl)-

There total 4 articles about Phosphinic chloride, phenyl(1-phenylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 461003-63-4
(1-methyl-1-phenylethyl)(phenyl)phosphinic acid ethyl ester

: 140458-23-7
α-methylbenzyl(phenyl)phosphinic chloride

Guidance literature:: (1-methyl-1-phenylethyl)(phenyl)phosphinic acid ethyl ester; With hydrogenchloride; In water;

With thionyl chloride; Further stages.;
DOI:10.1021/jo0202839

Reference yield:

: 66577-36-4
phenyl(1-phenylethyl)phosphinic acid

: 140458-23-7
α-methylbenzyl(phenyl)phosphinic chloride

Guidance literature:: With oxalyl dichloride; In dichloromethane;
DOI:10.1039/P19940003261

Reference yield:

: 2129-79-5
Benzylphenylphosphinsaeureethylester

: 140458-23-7
α-methylbenzyl(phenyl)phosphinic chloride

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / BuLi / hexane; tetrahydrofuran / 1.) -70 deg C, 30 min, 2.) warm to room temperature

2: 65 percent / conc. HCl / 14 h / Heating

3: oxalyl chloride / CH₂Cl₂

With hydrogenchloride; n-butyllithium; oxalyl dichloride; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/P19940003261