cis-(NC)CHCHSMe

Base Information

Chemical Name:cis-(NC)CHCHSMe
CAS No.:51245-71-7
Molecular Formula:C₄H₅NS
Molecular Weight:99.1564
Hs Code.:

Synonyms:

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Chemical Property of cis-(NC)CHCHSMe

Chemical Property:

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Technology Process of cis-(NC)CHCHSMe

There total 2 articles about cis-(NC)CHCHSMe which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 12080-10-3
[Fe(SMe)(CO)2(η-C5H5)]

: 1070-71-9
propiolonitrile

: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

: {Fe(CCCN)(η5-cyclopentadienyl)(carbonyl)2}

: trans-{(dicarbonylironcyclopentadienyl)C(CN)C(methylthiolato)(dicarbonylironcyclopentadienyl)}

: 51245-71-7
cis-(NC)CHCHSMe

Guidance literature:: In tetrahydrofuran; cyanoacetylene was condensed on to a THF soln. of Fe-complex frozen in liq. nitrogen, the mixt. was stirred as the temp. was slowly allowed to rise to room temp., 6 h under N2; filtn., solvent was evapd., the solid residue was dissolved in CH2Cl2, chromy. on a Florisil column, elution with CH2Cl2/hexane, CH2Cl2 and with CH2Cl2/THF, elem. anal.;
DOI:10.1016/0022-328X(89)87215-8

Reference yield:

: 12080-10-3
[Fe(SMe)(CO)2(η-C5H5)]

: 1070-71-9
propiolonitrile

: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

: {Fe(CCCN)(η5-cyclopentadienyl)(carbonyl)2}

: {C(O)C(CN)CH(SCH3)(η5-cyclopentadienylcarbonyliron)}

: trans-{(dicarbonylironcyclopentadienyl)C(CN)C(methylthiolato)(dicarbonylironcyclopentadienyl)}

: 51245-71-7
cis-(NC)CHCHSMe

Guidance literature:: In tetrahydrofuran; a THF soln. of cyanoacetylene was added to the THF soln. of Fe-complex at room temp., stirring for 6 h under N2; filtn., solvent was evapd., the solid residue was dissolved in CH2Cl2, chromy. on a Florisil column, elution with CH2Cl2/hexane, CH2Cl2 and with CH2Cl2/THF, elem. anal.;
DOI:10.1016/0022-328X(89)87215-8