[Fe2(μ-C(H)Bu(n))(μ-CO)(CO)2(.eta-C5H5)2]

Base Information

• Chemical Name: [Fe2(μ-C(H)Bu(n))(μ-CO)(CO)2(.eta-C5H5)2]
• CAS No.: 117144-60-2
• Molecular Formula: C₁₈H₂₀Fe₂O₃
• Molecular Weight: 396.049
• Mol file: 117144-60-2.mol

Synonyms:

Chemical Property of [Fe2(μ-C(H)Bu(n))(μ-CO)(CO)2(.eta-C5H5)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe2(μ-C(H)Bu(n))(μ-CO)(CO)2(.eta-C5H5)2]

There total 1 articles about [Fe2(μ-C(H)Bu(n))(μ-CO)(CO)2(.eta-C5H5)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{Et4N}{(H)tetracarbonyl iron} (25879-01-0) + {(C5H5)2(CO)2Fe2(CO)(CHCHCH2CH2CH3)}(1+)*PF6(1-) = {(C5H5)2(CO)2Fe2(CO)(CHCHCH2CH2CH3)}PF6 → cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + [Fe2(μ-C(H)Bu(n))(μ-CO)(CO)2(.eta-C5H5)2] (117144-60-2)

Guidance literature:

In tetrahydrofuran; a soln. of Et4N(HFe(CO)4) is transferred via cannula into a stirred soln. of diiron-compd. at -78-degree.C, after 30 min mixt. is allowed to warm to room temp.; solvent is removed on a rotary evaporator, residue is extd. with Et2O, soln. is filtered and evapd., residue is sublimed at 90°C and < 1E-3 mmHg and recrystd. from hexane at 0°C, elem. anal.;

Reference yield: 48.0%

[Fe2(μ-C(H)Bu(n))(μ-CO)(CO)2(.eta-C5H5)2] (117144-60-2) → cyclopentadienyl iron(II) dicarbonyl dimer (38117-54-3) + (Fe(C5H5)(CO))(CO)(CHCHCHCH2CH3)Fe(C5H5)

Guidance literature:

With (4,4'-dimethyl-1,1'-biphenyl); In benzene-d6; Irradiation (UV/VIS); a soln. of Fe-compd. and 4,4'-dimethylbiphenyl is photolyzed in a sealed NMR tube for 181 h; react. is followed by NMR;

upstream raw materials:

{Et₄N}{(H)tetracarbonyl iron}

Downstream raw materials:

cyclopentadienyl iron(II) dicarbonyl dimer

Refernces