1-(dicarbonylcyclopentadienylruthenium-σ-3,3,5,5-tetrafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienyliron

Base Information

• Chemical Name: 1-(dicarbonylcyclopentadienylruthenium-σ-3,3,5,5-tetrafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienyliron
• CAS No.: 84303-19-5
• Molecular Formula: C₁₄H₁₀F₄FeN₃O₄P₃Ru
• Molecular Weight: 610.083
• Mol file: 84303-19-5.mol

Synonyms:

Chemical Property of 1-(dicarbonylcyclopentadienylruthenium-σ-3,3,5,5-tetrafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienyliron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(dicarbonylcyclopentadienylruthenium-σ-3,3,5,5-tetrafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienyliron

There total 2 articles about 1-(dicarbonylcyclopentadienylruthenium-σ-3,3,5,5-tetrafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienyliron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(μ-carbonyl)(μ-3,3,5,5-tetrafluorocyclotriphosphazene-1,1-diyl)(carbonylcyclopentadienylruthenium)carbonylcyclopentadienyliron(Ru-Fe) (84303-20-8) → di(cyclopentadienideiron dicarbonyl) (38117-54-3) + bis[dicarbonylcyclopentadienylruthenium(I)] + (η(5)-C5H5)2FeRu(CO)4 (84280-02-4) + 1-(dicarbonylcyclopentadienylruthenium-σ-3,3,5,5-tetrafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienyliron (84303-19-5)

Guidance literature:

With CO; In tetrahydrofuran; High Pressure; (N2), 1100 psi CO, 120°C for 64 h; cooled to room temp. under high CO pressure, chromd. (silica gel), eluted with CH2Cl2/hexane, IR, NMR;

DOI:10.1021/ja00343a041

Reference yield:

potassium cyclopentadienyldicarbonyliron(0) + (1,3,3,5,5-pentafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienylruthenium (84303-17-3) → di(cyclopentadienideiron dicarbonyl) (38117-54-3) + (μ-carbonyl)(μ-3,3,5,5-tetrafluorocyclotriphosphazene-1,1-diyl)(carbonylcyclopentadienylruthenium)carbonylcyclopentadienyliron(Ru-Fe) (84303-20-8) + 1-(dicarbonylcyclopentadienylruthenium-σ-3,3,5,5-tetrafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienyliron (84303-19-5)

Guidance literature:

In tetrahydrofuran; (N2), soln. of the KFe-complex added dropwise to a soln. of the Ru-complex, stirred at 25°C in the absence of light for 48 h; removed, extd. with CH2Cl2, removed, dissolved in CH2Cl2/hexane (1/1), chromd. (hexane), Fe2(CO)4Cp2 eluted (CH2Cl2/hexane (1/10)), IR, eluted (CH2Cl2/hexane (4/6) and CH2Cl2), 2. band chromd. with toluene;

DOI:10.1021/ja00343a041

upstream raw materials:

(1,3,3,5,5-pentafluorocyclotriphos(P(V))azen-1-yl)dicarbonylcyclopentadienylruthenium

(μ-carbonyl)(μ-3,3,5,5-tetrafluorocyclotriphosphazene-1,1-diyl)(carbonylcyclopentadienylruthenium)carbonylcyclopentadienyliron(Ru-Fe)