[Cu(4,5-diphenyl-3,6-diazaocta-1,3,5,7-tetraene)(PPh₃)2]PF₆

Base Information

• Chemical Name: [Cu(4,5-diphenyl-3,6-diazaocta-1,3,5,7-tetraene)(PPh₃)2]PF₆
• CAS No.: 285116-45-2
• Molecular Formula: C₅₄H₄₆CuN₂P₂*F₆P
• Molecular Weight: 993.43
• Mol file: 285116-45-2.mol

Synonyms:

Chemical Property of [Cu(4,5-diphenyl-3,6-diazaocta-1,3,5,7-tetraene)(PPh₃)2]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cu(4,5-diphenyl-3,6-diazaocta-1,3,5,7-tetraene)(PPh₃)2]PF₆

There total 1 articles about [Cu(4,5-diphenyl-3,6-diazaocta-1,3,5,7-tetraene)(PPh₃)2]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + 4,5-diphenyl-3,6-diazaocta-1,3,5,7-tetraene hemihydrate + triphenylphosphine (603-35-0) → [Cu(4,5-diphenyl-3,6-diazaocta-1,3,5,7-tetraene)(PPh3)2]PF6 (285116-45-2)

Guidance literature:

In methanol; to soln. ligand in methanol solid (Cu(CH3CN)4)PF6 was added and stirredunder N2 atm. for 1 h, solid PPh3 was added and react. was stirred for 2 h under N2 atm.; solvent was evapd. under reduced pressure at 50°C, residue was triturated with Et2O, ppt. was filtered off, washed with Et2O, dried in vacuo over CaCl2 and recrystd. from CH2Cl2-hexane; elem. anal.;

DOI:10.1039/a909726k

upstream raw materials:

tetrakis(actonitrile)copper(I) hexafluorophosphate

triphenylphosphine