[(η6-ClC6H4COPh)tricarbonylchromium]

Base Information

• Chemical Name: [(η6-ClC6H4COPh)tricarbonylchromium]
• CAS No.: 934005-17-1
• Molecular Formula: C₁₆H₉ClCrO₄
• Molecular Weight: 352.694
• Mol file: 934005-17-1.mol

Synonyms:

Chemical Property of [(η6-ClC6H4COPh)tricarbonylchromium]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η6-ClC6H4COPh)tricarbonylchromium]

There total 3 articles about [(η6-ClC6H4COPh)tricarbonylchromium] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

n-butyllithium (109-72-8,29786-93-4) + tricarbonyl(η6-chlorobenzene)chromium (12082-03-0) + N-methoxy-N-methylbenzamide (6919-61-5) → [(η6-ClC6H4COPh)tricarbonylchromium] (934005-17-1)

Guidance literature:

In tetrahydrofuran; stirring of Cr(CO)3(ClC6H5) in THF at -78°C under N2; treatment with n-BuLi for 90 min; addn. of PhCON(Me)(OMe) via canula at -78°C; stirring for 2 h; addn. at 0°C to aq. AcOH; extn. with Et2O, with satd. K2CO3/H2O and with satd. NaCl/H2O soln.; evapn. of org. phase; chromy. (silica) with petroleum ether/CH2Cl2 mixt. 100/0 until 0/100 ratio; evapn. under reduced pressure, recrystn., elem. anal.;

DOI:10.1016/j.jorganchem.2006.10.055

Reference yield:

(2-chlorophenyl)(phenyl)methanone (5162-03-8) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → [(η6-ClC6H4COPh)tricarbonylchromium] (934005-17-1) + [(η6-ClC6H4COC6H5)tricarbonylchromium] (934005-17-1) + [(η6-ClC6H4)tricarbonylchromium](CO)[(η6-C6H5)tricarbonylchromium]

Guidance literature:

In not given;

DOI:10.1016/j.jorganchem.2006.10.055

Reference yield:

(2-chlorophenyl)(phenyl)methanone (5162-03-8) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → [(η6-ClC6H4COPh)tricarbonylchromium] (934005-17-1) + [(η6-ClC6H4COC6H5)tricarbonylchromium] (934005-17-1) + [(η6-ClC6H4)tricarbonylchromium](CO)[(η6-C6H5)tricarbonylchromium]

Guidance literature:

In not given;

DOI:10.1016/j.jorganchem.2006.10.055

upstream raw materials:

n-butyllithium

tricarbonyl(η6-chlorobenzene)chromium

N-methoxy-N-methylbenzamide

(2-chlorophenyl)(phenyl)methanone