12082-03-0

Basic information

• Product Name: Chromium, tricarbonyl(h6-chlorobenzene)-
• Synonyms: (Chlorobenzene)chromiumtricarbonyl (6CI); Chromium, tricarbonyl(chlorobenzene)- (7CI,8CI); Benzene,chloro-, chromium complex; (h6-Chlorobenzene)tricarbonylchromium; Chlorobenzenetricarbonylchromium;Tricarbonyl(chlorobenzene)chromium; Tricarbonyl(h6-chlorobenzene)chromium; Tricarbonyl(h6-phenyl chloride)chromium
• CAS NO: 12082-03-0
• Molecular Formula: C9H5 Cl Cr O3
• Molecular Weight: 248.586
• Mol File: 12082-03-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Chromium, tricarbonyl(h6-chlorobenzene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Chromium, tricarbonyl(h6-chlorobenzene)-(12082-03-0)
• EPA Substance Registry System: Chromium, tricarbonyl(h6-chlorobenzene)-(12082-03-0)

Safety Data

• Hazardous Substances Data: 12082-03-0(Hazardous Substances Data)

Upstream product

• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 108-90-7 chlorobenzene 

Downstream Products

• 12116-44-8 (η6-anisol)tricarbonyl chromium 
• 38117-54-3 cyclopentadienyl iron(II) dicarbonyl dimer 
• 697302-50-4 (benzene)tricarbonylchromium 
• 62010-71-3 (η(5)-Cp)Fe(CO)2(η(1),η(6)-C6H5)Cr(CO)3 
• 73038-78-5 diphenylacetonitrile(tricarbonyl)chromium 
• 31943-94-9 chlorobenzene chromium dicarbonyl triphenylphosphine 
• 93-58-3 benzoic acid methyl ester 
• 14917-12-5 triphenylphosphine chromium pentacarbonyl 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 32714-15-1 ClC₆H₅Cr(CO)2As(C₆H₅)3 
• 63256-47-3 1,2-C2B10H10-1-(OC)3Cr(η-C6H5)-2-C6H5 
• 335358-05-9 η7-(dimethyl phenyl phosphite)dicarbonylchromium (0) 
• 125840-67-7 η6-(α-chloro,α-para-tosyl)methylobenzene-tricarbonylchromium(0) 
• 194302-72-2 tricarbonyl(η(6)-(2-(1-hydroxycyclohexyl)ethynyl)benzene)chromium(0) 

Relevant articles and documents

The study of catalyst effects on the complexation of arenes with Cr(CO)6. An overview

New results from our thorough investigation of different catalystic effects on the rate and yields of complexation of arenes with Cr(CO) are presented with a short review of the subject.With decalin as solvent the following substances were found to be the best catalysts: butyl acetate, ethyl formate, and dimethyl succinate.Butyl acetate proved to be the catalyst also in di-n-butyl ether.Special attention was paid to the complexation of naphthalene, and chlorobenzene.Some unsuccessful attempts at asymmetric induction of complexation are also described.

An improved method for the synthesis of η6-arenetricarbonylchromium complexes

A novel apparatus for the complexation of arenes with Cr(CO)6 is described.This, and the modification of the reaction procedure shortens the reaction time, and improves the yields of η6-arenetricarbonylchromium complexes.The method was tested f