[(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(2,6-dimethylphenyl isocyanide)3]

Base Information

• Chemical Name: [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(2,6-dimethylphenyl isocyanide)3]
• CAS No.: 1352439-29-2
• Molecular Formula: C₅₇H₅₇FeN₅S
• Molecular Weight: 900.026
• Mol file: 1352439-29-2.mol

Synonyms:

Chemical Property of [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(2,6-dimethylphenyl isocyanide)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(2,6-dimethylphenyl isocyanide)3]

There total 2 articles about [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(2,6-dimethylphenyl isocyanide)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) + [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)] (1352439-25-8) → [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(2,6-dimethylphenyl isocyanide)3] (1352439-29-2)

Guidance literature:

In diethyl ether; hexane; under N2; a soln. of a ligand (0.30 mmol) in n-hexane was layered on a soln. of Fe-contg. compd. (0.10 mmol) in diethyl ether; slow diffusion over 2 d; elem. anal.;

DOI:10.1021/om201010a

Reference yield: 21.0%

2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) + [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)] (1352439-25-8) → [(N-mesityl-o-amidobenzenethiolato)Fe(2,6-dimethylphenyl isocyanide)3] (1352439-30-5) + [(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(2,6-dimethylphenyl isocyanide)3] (1352439-29-2)

Guidance literature:

In tetrahydrofuran; under N2; to a soln. of Fe-contg. compd. (0.10 mmol) in THF was added a ligand (0.30 mmol) at room temp.; stirring overnight; the soln. was filtered and the filtrate was concd.; slow evapn. of THF; elem. anal.;

DOI:10.1021/om201010a

upstream raw materials:

2,6-dimethylphenyl isonitrile

[(N,N'-dimesityl-2,2'-diamidophenyl sulfide-2H)Fe(tetrahydrofuran)]