p-tolyldimethylbismuthane

Base Information

Chemical Name:p-tolyldimethylbismuthane
CAS No.:104202-61-1
Molecular Formula:C₉H₁₃Bi
Molecular Weight:330.183
Hs Code.:

Synonyms:

Suppliers and Price of p-tolyldimethylbismuthane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of p-tolyldimethylbismuthane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of p-tolyldimethylbismuthane

There total 2 articles about p-tolyldimethylbismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 106-38-7
para-bromotoluene

: 7529-35-3
dimethylbismuthanyl bromide

: 7439-93-2
lithium

: 104202-61-1
p-tolyldimethylbismuthane

Guidance literature:: In tetrahydrofuran; byproducts: Me4Bi2, Me3Bi; (Ar); Li was added to a soln. of Me2BiBr at -78°C, vigorous stirred (1.5 h), p-Br-toluene (20 % excess) added, stirred (-78°C, 20 min); filtered, solvent removed (-30--10°C), extracted (cold pentane); solvent was removed; recondensed (0.01 mbar); elem. anal.;

Reference yield:

: sodium dimethylbismuthide

: 106-38-7
para-bromotoluene

: 104202-61-1
p-tolyldimethylbismuthane

: 82783-70-8
tetramethyldibismuthane

Guidance literature:: In ammonia; byproducts: NaBr, NaNH2, toluene;

Reference yield:

: 104202-61-1
p-tolyldimethylbismuthane

: 104202-64-4
di(p-tolyl)methylbismuthane

Guidance literature:: byproducts: Me3Bi; treated after 3 weeks with slow N2 stream at room temp., warmed at approx. 90°C; lower yields of reaction at room temperature after 1 d, under exclusion of light after 5-6 d; cooled; elem. anal.;

upstream raw materials:

para-bromotoluene

dimethylbismuthanyl bromide

lithium