PdCl₂(P(C₆H₅)3)(CH₃OC₆H₄NCCHNC₆H₄OCH₃)Pd(C₄H₇)

Base Information

• Chemical Name: PdCl₂(P(C₆H₅)3)(CH₃OC₆H₄NCCHNC₆H₄OCH₃)Pd(C₄H₇)
• CAS No.: 81111-61-7
• Molecular Formula: C₃₈H₃₇Cl₂N₂O₂PPd₂
• Molecular Weight: 868.444
• Mol file: 81111-61-7.mol

Synonyms:

Chemical Property of PdCl₂(P(C₆H₅)3)(CH₃OC₆H₄NCCHNC₆H₄OCH₃)Pd(C₄H₇)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PdCl₂(P(C₆H₅)3)(CH₃OC₆H₄NCCHNC₆H₄OCH₃)Pd(C₄H₇)

There total 5 articles about PdCl₂(P(C₆H₅)3)(CH₃OC₆H₄NCCHNC₆H₄OCH₃)Pd(C₄H₇) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(2-methylallyl)palladium-chloride dimer + [PdCl(C(NC6H4OCH3)CHNC6H4OCH3)(P(C6H5)3)2] → chloro(η3-2-methylallyl)(triphenylphosphine)palladium(II) + PdCl2(P(C6H5)3)(CH3OC6H4NCCHNC6H4OCH3)Pd(C4H7) (81111-61-7)

Guidance literature:

In 1,2-dichloro-ethane; soln. of PdCl(C(NC6H4OMe)CHNC6H4OMe)(PPh3)2 in (CH2Cl)2 treated with (PdCl(MeC3H4))2 for ca. 20 min; concd. in vac., Et2O added, solid re-pptd. from the same solvents, mother-liquor concd., Et2O/n-hexane added;

DOI:10.1016/S0022-328X(00)85578-3

Reference yield: 65.0%

sodium perchlorate monohydrate (7791-07-3) + (PdCl(η3-2MeC3H4))2 + trans-{chloro(1,4-bis(p-methoxyphenyl)-1,4-diaza-1,3-butadiene-2-yl)bis(triphenylphosphine)palladium(II)} → chloro(η3-2-methylallyl)(triphenylphosphine)palladium(II) + PdCl2(P(C6H5)3)(CH3OC6H4NCCHNC6H4OCH3)Pd(C4H7) (81111-61-7) + PdCl(P(C6H5)3)2CNC6H4OCH3CHNC6H4OCH3PdCH2CCH3CH2(1+)*ClO4(1-)=PdCl(P(C6H5)3)2CNC6H4OCH3CHNC6H4OCH3PdCH2CCH3CH2ClO4

Guidance literature:

In methanol; dichloromethane; byproducts: NaCl; a soln. of Pd-dimer in CH2Cl2 was treated with Pd-complex at 0°C, NaClO4*H2O in MeOH was added, stirred for 5 min; the mixt. was worked-up at room temp. as quick as possible, evapd. to dryness, the residue was treated with CH2Cl2 and charcoal, filtered, concd., Et2O was added, recrystd. from CH2Cl2-Et2O; elem. anal.;

DOI:10.1039/DT9820001715

Reference yield:

(C2H5)3N(CH2C6H5)(1+)*PdCl2(C3H4CH3)(1-)=(C2H5)3N(CH2C6H5)[PdCl2(C3H4CH3)] (76096-87-2) + Cl(P(C6H5)3)2Pd(C2N2H(C6H4OCH3)2)Pd(C3H4CH3)(1+)*ClO4(1-)=(Cl(P(C6H5)3)2Pd(C2N2H(C6H4OCH3)2)Pd(C3H4CH3))ClO4 (76096-89-4) → chloro(η3-2-methylallyl)(triphenylphosphine)palladium(II) + Cl2(P(C6H5)3)Pd(C2N2H(C6H4OCH3)2)Pd(C3H4CH3) (81111-61-7)

Guidance literature:

With tetrabutylammonium perchlorate; In dichloromethane; 30 °C, ionic concn. 3E-2 mol dm**-3; followed spectrophotometrically; Kinetics;

DOI:10.1039/DT9820002303

upstream raw materials:

Pd(P(C₆H₅)3)2Cl(C₁₆H₁₅N₂O₂)Pd(C₃H₄CH₃)⁽¹⁺⁾*ClO₄^(1-)=[Pd(P(C₆H₅)3)2Cl(C₁₆H₁₅N₂O₂)Pd(C₃H₄CH₃)]ClO₄

(C₂H₅)3N(CH₂C₆H₅)⁽¹⁺⁾*PdCl₂(C₃H₄CH₃)^(1-)=(C₂H₅)3N(CH₂C₆H₅)[PdCl₂(C₃H₄CH₃)]

Pd₂(P(C₆H₅)3)(S₂CN(CH₃)2)(C₁₆H₁₅N₂O₂)(C₄H₇)⁽¹⁺⁾*ClO₄^(1-)=[Pd₂(P(C₆H₅)3)(S₂CN(CH₃)2)(C₁₆H₁₅N₂O₂)(C₄H₇)]ClO₄

sodium perchlorate monohydrate