7791-07-3 Usage
Description
Sodium perchlorate monohydrate is the inorganic compound with the chemical formula NaClO4?H2O. It is the commom existence form of sodium perchlorate, which can gradualy absorbe water in the air to form the monohydrate. Sodium perchlorate monohydrate is white rhombic crystal and highly soluble in water and in alcohol. It is a stronge oxidiser and may cause damage to organs through prolonged or repeated exposure. It is a chaotropic agent used in standard DNA extraction and hybridization reactions in molecular biology. It is widely utilized as a deproteinization agent during nucleic acid synthesis. It can also be used as a chemical sensitizing agent for some modern commercial explosives products.
References
1.https://pubchem.ncbi.nlm.nih.gov/compound/Sodium_perchlorate_monohydrate#section=Chemical-Vendors
2.https://en.wikipedia.org/wiki/Sodium_perchlorate
3.http://www.arkema.com/export/shared/.content/media/downloads/socialresponsability/safety-summuries/Hydrogen-Peroxides-Sodium-Perchlorate-GPS-2014-12-15-V0.pdf
4.http://www.sciencelab.com/msds.php?msdsId=9927599
Uses
Sodium Perchlorate monohydrate is the hydrate salt of Perchloric Acid (P286000). Sodium Perchlorate monohydrate electrochemical synthesis as it is a strong oxidizing agent.
General Description
Sodium perchlorate monohydrate (NaClO4· H2O) is a hydrated sodium salt. Its crystal structure has been investigated by three-dimensional single crystal x-ray diffraction studies. Its crystals belong to the monoclinic crystal system having space group C2/c.
Check Digit Verification of cas no
The CAS Registry Mumber 7791-07-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,7,9 and 1 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 7791-07:
(6*7)+(5*7)+(4*9)+(3*1)+(2*0)+(1*7)=123
123 % 10 = 3
So 7791-07-3 is a valid CAS Registry Number.
InChI:InChI=1/ClHO4.Na.H2O/c2-1(3,4)5;;/h(H,2,3,4,5);;1H2/q;+1;/p-1
7791-07-3Relevant articles and documents
Kinetics of oxidation of ascorbic acid and 1,4-dihydroxybenzene by semiquinone radical bound to ruthenium(II)
Ghosh, Debjani,Shukla, Atindra D.,Banerjee, Rupendranath,Das, Amitava
, p. 1220 - 1225 (2007/10/03)
In 40% (v/v) MeOH-H2O media, containing [H+] (0.001-0.038 mol dm-3), the semiquinone (sq) radical, bound to Ru(II) in [Ru(bpy)2(sq)]+ 1, oxidises ascorbic acid (H2A) to dehydroascorbic acid (A), and 1,4-dihydroxybenzene (H2Q) to p-benzoquinone (Q); 1 is itself reduced to [Ru(bpy)2(Hcat)]+ 2H. The reactions are centred at sq not Ru(II). The sq/cat couple in 1 is reversible and its E1/2 increases with increasing [H+]; rate of chemical reduction of 1 to 2H increases in parallel. Rate increases also with increasing mole percent of D2O in the solvent suggesting a preliminary protonation equilibrium producing 1H, in which a H+ binds to the π-electron cloud of Ru(II)-bound sq. Under the experimental conditions, the kinetically significant species are 1H, H2Q, H2A and HA-. The kinetic activity of HA- ion is only ≈200 times more than that of H2A. This testifies against a purely outer-sphere mechanism and suggests significant electronic interaction between the redox partners. Increased percentage of MeOH in the solvent decreases λmax for the LMCT band; reaction rate for ascorbic acid decreases in parallel.