Ni(CO)3(SbCl(C₆H₅)2)

Base Information

• Chemical Name: Ni(CO)3(SbCl(C₆H₅)2)
• CAS No.: 128091-44-1
• Molecular Formula: C₁₅H₁₀ClNiO₃Sb
• Molecular Weight: 454.136

Synonyms:

Chemical Property of Ni(CO)3(SbCl(C₆H₅)2)

Chemical Property:

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Technology Process of Ni(CO)3(SbCl(C₆H₅)2)

There total 2 articles about Ni(CO)3(SbCl(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

[NMe4]2[Ni6(CO)6(μ-CO)6] + diphenylantimony(III) chloride (2629-47-2) → Ni2(CO)4(μ-Ph2SbOSbPh2)2 + Ni(CO)3(SbCl(C6H5)2) (128091-44-1) + 2(CH3)4N(1+)*Ni10(SbC6H5)2(CO)18(2-)*2(CH3)2CO={(CH3)4N}2{Ni10(SbC6H5)2(CO)18}*2(CH3)2CO

Guidance literature:

In tetrahydrofuran; under Ar or N2; addn. of Ph2SbCl in THF to slurry of Ni-compound in THF, stirred (room temp., 2 h), monitored by IR; evapn. (oily brown residue), extn. (hexane, toluene, THF), THF extract: evapn., crystn. (acetone), byproducts from yellow hexane extract, slow evapn.;

DOI:10.1016/0022-328X(90)85153-P

Reference yield:

[NMe3Ph]2[Ni6(CO)6(μ-CO)6] + diphenylantimony(III) chloride (2629-47-2) → Ni2(CO)4(μ-Ph2SbOSbPh2)2 + Ni(CO)3(SbCl(C6H5)2) (128091-44-1) + 2N(CH3)3(C6H5)(1+)*Ni10(SbC6H5)2(CO)18(2-)={N(CH3)3(C6H5)}2{Ni10(SbC6H5)2(CO)18}

Guidance literature:

In tetrahydrofuran; under Ar or N2; addn. of Ph2SbCl in THF to slurry of Ni-compound in THF, color change cherry-red to brown, stirred (room temp., 2 h), monitored by IR; evapn. (oily brown residue), extn. (hexane, toluene, THF), main product from THF extract, by-products from yellow hexane extract, slow evapn.;

DOI:10.1016/0022-328X(90)85153-P

upstream raw materials:

diphenylantimony(III) chloride

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