chloro(diphenyl)stibane

Base Information

• Chemical Name: chloro(diphenyl)stibane
• CAS No.: 2629-47-2
• Molecular Formula: C12H10 Cl Sb
• Molecular Weight: 311.414
• Mol file: 2629-47-2.mol

Synonyms:Chlorodiphenylantimony;Chlorodiphenylstibine; Diphenylantimony chloride; Diphenylantimony(III)chloride; Diphenylchlorostibine; Diphenylstibinous chloride

Chemical Property of chloro(diphenyl)stibane

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.20260

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of chloro(diphenyl)stibane

There total 38 articles about chloro(diphenyl)stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

antimony(III) chloride (10025-91-9) + triphenylantimony (603-36-1) → diphenylantimony(III) chloride (2629-47-2)

Guidance literature:

In neat (no solvent); for 72h;

DOI:10.1002/anie.201801452

Reference yield: 99.0%

triphenylantimony (603-36-1) + bismuth(III) chloride (7787-60-2) → diphenylantimony(III) chloride (2629-47-2)

Guidance literature:

In chloroform; reflux under CO2;

Reference yield: 90.0%

diphenylantimony(V) trichloride * x H2O → diphenylantimony(III) chloride (2629-47-2)

Guidance literature:

With SnCl₂; In hydrogenchloride; ethanol; dissolving of (C6H5)2SbCl3*xH2O (0.02 mol) under reflux in ethanol and 10% HCl; addn. of anhydrous SnCl2; refluxing; cooling;; crystallization on standing overnight; filtration; washing with dilute HCl and ethanol; drying in vac.; elem. anal.;;

DOI:10.1016/0022-328X(92)83160-J

upstream raw materials:

triphenylantimony

bismuth(III) chloride

antimony(III) chloride

triphenylbismuthane

Downstream raw materials:

biphenyl

(1E)-1,3-diphenylpropene

(E)-cinnamyl phenyl ether

cinnamic nitrile

Refernces

• 1、 W?chtler, Erik,Gericke, Robert,Block, Theresa,Gerke, Birgit,P?ttgen, Rainer,Wagler, J?rg. "Compounds of the types Pn(pyS)3(Pn = P, As, Bi; PyS: Pyridine-2-thiolate) and Sb(pyS)xPh3-x(x = 3-1); Molecular structures and electronic situations of the Pn atoms". . p. 103 - 118. Retrieved 2021.
• 2、 Taylor, William V.,Xie, Zhu-Lin,Cool, Nicholas I.,Shubert, Sofia A.,Rose, Michael J.. "Syntheses, Structures, and Characterization of Nickel(II) Stibines: Steric and Electronic Rationale for Metal Deposition". . p. 10364 - 10374. Retrieved 2018/08/28.