[(η1-p-MeC6H4NN)Mo(η2-diethyldithiocarbamato)3]*(diethyl ether)

Base Information

• Chemical Name: [(η1-p-MeC6H4NN)Mo(η2-diethyldithiocarbamato)3]*(diethyl ether)
• CAS No.: 929219-00-1
• Molecular Formula: C₄H₁₀O*C₂₂H₃₇MoN₅S₆
• Molecular Weight: 734.028
• Mol file: 929219-00-1.mol

Synonyms:

Chemical Property of [(η1-p-MeC6H4NN)Mo(η2-diethyldithiocarbamato)3]*(diethyl ether)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η1-p-MeC6H4NN)Mo(η2-diethyldithiocarbamato)3]*(diethyl ether)

There total 1 articles about [(η1-p-MeC6H4NN)Mo(η2-diethyldithiocarbamato)3]*(diethyl ether) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

cis-dioxobis(diethyldithiocarbamato)molybdenum(VI) + diethyl ether (60-29-7,927820-24-4) + [(η-5-cyclopentadienyl)(η6-(p-tolyl)hydrazine)iron(II)] hexafluorophosphate (178443-84-0) + sodium diethyldithiocarbamate trihydrate (20624-25-3) → [(η1-p-MeC6H4NN)Mo(η2-diethyldithiocarbamato)3]*(diethyl ether) (929219-00-1) + [(η5-C5H5)Fe(μ,η6:η1-MeC6H4NN)Mo(η2-diethyldithiocarbamato)3]PF6

Guidance literature:

In methanol; (N2); a soln. of Fe complex added dropwise to a suspn. of Mo complex andNa salt, refluxed; cooled to room temp. and concd. (vac.), filtered out, dissolved in CH2Cl2, percolated through a column contg. silica gel in hexane, eluted with Et2O, Et2O/CH2Cl2, CH2Cl2; evapd. (vac.); elem. anal.;

DOI:10.1021/ic0613098

upstream raw materials:

diethyl ether

[(η-5-cyclopentadienyl)(η6-(p-tolyl)hydrazine)iron(II)] hexafluorophosphate

sodium diethyldithiocarbamate trihydrate