chloro(phenyl)cyclopentadienylphosphine

Base Information

Chemical Name:chloro(phenyl)cyclopentadienylphosphine
CAS No.:90285-17-9
Molecular Formula:C₁₁H₁₀ClP
Molecular Weight:208.627
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of chloro(phenyl)cyclopentadienylphosphine

Chemical Property:

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Technology Process of chloro(phenyl)cyclopentadienylphosphine

There total 1 articles about chloro(phenyl)cyclopentadienylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 34822-90-7
cyclopentadienylthallium

: 644-97-3
Dichlorophenylphosphine

: 90285-17-9
chloro(phenyl)cyclopentadienylphosphine

Guidance literature:: In tetrahydrofuran; at -80 - -40 ℃;

Reference yield:

: 109-72-8,29786-93-4
n-butyllithium

: 15038-48-9,17731-95-2
tris(acetonitrile)tricarbonylmolybdenum⁽⁰⁾

: 624-73-7
1,2-Diiodoethane

: tris(dibenzylidene acetone)dipalladium⁽⁰⁾

: 90285-17-9
chloro(phenyl)cyclopentadienylphosphine

: meso-[Pd(μ-I)[Mo(CO)3(η5-C5H4(PBuPh))]]2

: rac-dl-[Pd(μ-I)[Mo(CO)3(η5-C5H4(PBuPh))]]2

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; under Ar; BuLi in hexane was added at 0°C to the phosphine in THF, after 30 min (MeCN)3Mo(CO)3 added, stirred overnight at room temp., refluxed for 2 h, cooled to room temp., ICH2CH2I added, stirred for 1 h, Pd2(dba)3 added, stirred for 1 h; Celite was added to the soln., solvent evapd. under vac., residue chromd. on a silica column with hexane-CH2Cl2 (4:6) as eluent, eluate evapd., residue recrystd. from CH2Cl2-pentane (liq. diffn.) at room temp. to give the pure meso-form of the complex;
DOI:10.1021/om0400595