624-73-7Relevant articles and documents
Carbodeoxygenation of biomass: The carbonylation of glycerol and higher polyols to monocarboxylic acids
Coskun, Timur,Conifer, Christopher M.,Stevenson, Laura C.,Britovsek, George J. P.
supporting information, p. 6840 - 6844 (2013/07/05)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation forms butyric and isobutyric acid. At low HI concentration, the intermediate allyl iodide undergoes carbonylation to give vinyl acetic acid and crotonic acid. Higher polyols CnH n+2(OH)n are carbonylated to the corresponding C n+1 mono-carboxylic acids. Copyright
Reactions of trimethyliodosilane with mono-, di-, and trioxacycloalkanes
Voronkov, M. G.,Dubinskaya, E. I.
, p. 13 - 32 (2007/10/02)
The reactions of Me3SiI with mono-, di-, and trioxacycloalkanes have been studied first.Preparative methods for the synthesis of some promising synthones, namely α,ω-diiodoalkanes, α,ω-alkanediols, and iodomethyl ω-iodoalkyl ethers, have been developed based on these reactions.The effect of the cycle size and the nature of the substituent on the course of the reactions is demonstrated.Schemes for the mechanism of the reactions are suggested.
Halogenobis(N,N-dialkyldithiocarbamato)iron(III) Complexes as Potential Catalysts for Halogen Addition Reactions to Alkenes
Tsipis, Constantinos A.,Katsoulos, George A.,Vakoulis, Fotios D.
, p. 1404 - 1405 (2007/10/02)
In the presence of a catalytic amount of iron(III) halogenobisdithiocarbamates, the addition of molecular halogens to alkenes occurs rapidly to afford cis-addition products.