bis(N,N'-diphenylbenzamidine)platinum(II)

Base Information

• Chemical Name: bis(N,N'-diphenylbenzamidine)platinum(II)
• CAS No.: 112187-07-2
• Molecular Formula: C₃₈H₃₀N₄Pt
• Molecular Weight: 737.763
• Mol file: 112187-07-2.mol

Synonyms:

Chemical Property of bis(N,N'-diphenylbenzamidine)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(N,N'-diphenylbenzamidine)platinum(II)

There total 1 articles about bis(N,N'-diphenylbenzamidine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + n-butyllithium (109-72-8,29786-93-4) + N,N'-diphenylbenzamidine (2556-46-9,141417-98-3) → bis(N,N'-diphenylbenzamidine)platinum(II) (112187-07-2)

Guidance literature:

In diethyl ether; hexane; the ligand in Et2O was cooled to 0°C and LiBu(n) in hexane was added, warmed to ambient temp. with stirring for 30 min, the soln. was frozen to -196°C, solid Pt-complex was added, the mixt. was allowed to reach to room temp.; after 16 h the mixt. was filtered, the solid was washed with CH2Cl2, the extracts added to the filtrate, evapd. to dryness, recrystd. from CH2Cl2; elem. anal.;

DOI:10.1039/DT9870002687

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

n-butyllithium

N,N'-diphenylbenzamidine