Rh(η4-cyclooctadiene)((κ2-N,N'-2,6-diisopropylphenyl-N)2(CNCy2))

Base Information

• Chemical Name: Rh(η4-cyclooctadiene)((κ2-N,N'-2,6-diisopropylphenyl-N)2(CNCy2))
• CAS No.: 1071873-65-8
• Molecular Formula: C₄₅H₆₈N₃Rh
• Molecular Weight: 753.961
• Mol file: 1071873-65-8.mol

Synonyms:

Chemical Property of Rh(η4-cyclooctadiene)((κ2-N,N'-2,6-diisopropylphenyl-N)2(CNCy2))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh(η4-cyclooctadiene)((κ2-N,N'-2,6-diisopropylphenyl-N)2(CNCy2))

There total 2 articles about Rh(η4-cyclooctadiene)((κ2-N,N'-2,6-diisopropylphenyl-N)2(CNCy2)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + [K(((2,6-diisopropylphenyl)N)2CNCy2)] → [Rh(η4-cyclooctadiene)]4(μ4-O2SiMe2)2 + Rh(η4-cyclooctadiene)((η5-2,6-diisopropylphenyl-N)(2,6-diisopropylphenyl)N(CNCy2)) (1071873-65-8,1071873-54-5)

Guidance literature:

In toluene; byproducts: KCl; (under N2 or Ar, Schlenk); suspn. of K-salt in toluene added to soln. ofRh-complex in toluene at -78°C over 10 min, warmed to 20° C for 2 h, stirred for 1 h; volatiles removed in vacuo, residue extd. with hexane, filtered, filtrate concd., stored at -30°C overnight; elem. anal.;

DOI:10.1039/b806542j

Reference yield: 29.0%

Rh(η4-cyclooctadiene)((η5-2,6-diisopropylphenyl-N)(2,6-diisopropylphenyl)N(CNCy2)) (1071873-65-8,1071873-54-5) → Rh(η4-cyclooctadiene)((κ2-N,N'-2,6-diisopropylphenyl-N)2(CNCy2)) (1071873-65-8,1071873-54-5)

Guidance literature:

In toluene; (under N2 or Ar, Schlenk); soln. of Rh-complex in toluene heated at 80°C for 5 h; volatiles removed in vacuo, residue extd. with hexane, filtered, filtrate concd., stored at -30°C overnight;

DOI:10.1039/b806542j

Reference yield: 29.0%

Rh(η4-cyclooctadiene)((η5-2,6-diisopropylphenyl-N)(2,6-diisopropylphenyl)N(CNCy2)) (1071873-65-8,1071873-54-5) → Rh(η4-cyclooctadiene)((κ2-N,N'-2,6-diisopropylphenyl-N)2(CNCy2)) (1071873-65-8,1071873-54-5)

Guidance literature:

In toluene; (under N2 or Ar, Schlenk); soln. of Rh-complex in toluene heated at 80°C for 5 h; volatiles removed in vacuo, residue extd. with hexane, filtered, filtrate concd., stored at -30°C overnight;

DOI:10.1039/b806542j

upstream raw materials:

Rh(η4-cyclooctadiene)((η5-2,6-diisopropylphenyl-N)(2,6-diisopropylphenyl)N(CNCy2))

Downstream raw materials:

Rh(η4-cyclooctadiene)((κ2-N,N'-2,6-diisopropylphenyl-N)2(CNCy2))