C₂₁H₂₇ClO₂

Base Information

• Chemical Name: C₂₁H₂₇ClO₂
• CAS No.: 127229-35-0
• Molecular Formula: C₂₁H₂₇ClO₂
• Molecular Weight: 346.897
• Mol file: 127229-35-0.mol

Synonyms:

Chemical Property of C₂₁H₂₇ClO₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of C₂₁H₂₇ClO₂

There total 2 articles about C₂₁H₂₇ClO₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Methyl-1-pentene (763-29-1) + (CH3OC6H4)2CH(1+)*BCl4(1-) = (CH3OC6H4)2CHBCl4 → C21H27ClO2 (127229-35-0)

Guidance literature:

In dichloromethane; at -70 ℃; Rate constant; Thermodynamic data; ΔH(excit.), ΔS(excit.), ΔG(excit.); also in the presence of benzyltriethylammonium tetrachloroborate; var. concentration of reactants, other solvents;

DOI:10.1021/ja00167a049

Reference yield:

2-Methyl-1-pentene (763-29-1) + 4,4'-dimethoxydiphenylmethyl chloride (7525-23-7) → C21H27ClO2 (127229-35-0)

Guidance literature:

With boron trichloride; Thermodynamic data; Rate constant; 1) CH2Cl2, 2) CH2Cl2, -70 deg C; velocity const. of reaction: carbenium ion with 2-methyl-1-pentene, variation of educt-conc. and reagent, kinetics, ΔH(excit.), ΔS(excit.), ΔG(excit.), influence of subst. to reactivity;

upstream raw materials:

2-Methyl-1-pentene

4,4'-dimethoxydiphenylmethyl chloride

Refernces

• 1、 Schneider, Reinhard,Grabis, Ute,Mayr, Herbert. "Direkte Bestimmung der Additionsgeschwindigkeiten von Carbenium-Ionen an Alkene". . p. 94 - 95. Retrieved 2007/10/02.