tin(IV)tetraphenylporphyrinato bis(trifluoromethanesulfonate)

Base Information

• Chemical Name: tin(IV)tetraphenylporphyrinato bis(trifluoromethanesulfonate)
• CAS No.: 129997-24-6
• Molecular Formula: C₄₆H₂₈F₆N₄O₆S₂Sn
• Molecular Weight: 1029.58
• Mol file: 129997-24-6.mol

Synonyms:

Chemical Property of tin(IV)tetraphenylporphyrinato bis(trifluoromethanesulfonate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tin(IV)tetraphenylporphyrinato bis(trifluoromethanesulfonate)

There total 3 articles about tin(IV)tetraphenylporphyrinato bis(trifluoromethanesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-dihydroxo(meso-tetraphenylporphyrinato)tin(IV) (26334-89-4) → tin(IV)tetraphenylporphyrinato bis(trifluoromethanesulfonate) (129997-24-6)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform

2: chloroform-d1

In chloroform-d1; chloroform;

DOI:10.1021/ic902265e

Reference yield:

dichloro(5,10,15,20-tetraphenylporphyrinato)tin(IV) (26334-85-0) + silver trifluoromethanesulfonate (2923-28-6) → tin(IV)tetraphenylporphyrinato bis(trifluoromethanesulfonate) (129997-24-6)

Guidance literature:

In tetrahydrofuran; byproducts: AgCl; to soln. of tetraphenylporphyrinato SnCl2 in THF added AgCF3SO3 at 55°C; soln. stirred at this temp. for 30 min; ppt. of AgCl filtered off; soln. evapd. moderately; complex extd. with CH2Cl2; crystd. by evapn. ofsolvent at room temp.;

DOI:10.1016/j.molcata.2004.05.004

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + [Sn(meso-tetraphenylporphyrinato)(3-methoxyphenolato)2] (1210043-22-3) → tin(IV)tetraphenylporphyrinato bis(trifluoromethanesulfonate) (129997-24-6)

Guidance literature:

In chloroform-d1; at 25°C; not isolated, detected by NMR;

DOI:10.1021/ic902265e

upstream raw materials:

dichloro(5,10,15,20-tetraphenylporphyrinato)tin(IV)

silver trifluoromethanesulfonate

trifluorormethanesulfonic acid

[Sn(meso-tetraphenylporphyrinato)(3-methoxyphenolato)2]

Downstream raw materials:

Sn{((C₆H₅)CC₄H₂N)4}(OCOH)(OSO₂CF₃)