(1R,2S,6S,7R,8R)-7-((2R,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.0^2,6]undecane

Base Information

• Chemical Name: (1R,2S,6S,7R,8R)-7-((2R,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.0^2,6]undecane
• CAS No.: 129885-85-4
• Molecular Formula: C₃₆H₄₂O₉
• Molecular Weight: 618.724
• Mol file: 129885-85-4.mol

Synonyms:

Chemical Property of (1R,2S,6S,7R,8R)-7-((2R,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.0^2,6]undecane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1R,2S,6S,7R,8R)-7-((2R,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.0^2,6]undecane

There total 2 articles about (1R,2S,6S,7R,8R)-7-((2R,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.0^2,6]undecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl dimethylphosphinothioate (129885-86-5) + 1,6-anhydro-3,4-O-isopropylidene-β-D-galactopyranose (52579-97-2) → (1R,2S,6S,7R,8R)-7-((2S,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.02,6]undecane (129885-85-4) + (1R,2S,6S,7R,8R)-7-((2R,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.02,6]undecane (129885-85-4)

Guidance literature:

With molecular sieve; triphenylmethyl perchlorate; In benzene; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1246/cl.1990.849

Reference yield:

3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl dimethylphosphinothioate (129885-86-5) + 1,6-anhydro-3,4-O-isopropylidene-β-D-galactopyranose (52579-97-2) → (1R,2S,6S,7R,8R)-7-((2S,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.02,6]undecane (129885-85-4) + (1R,2S,6S,7R,8R)-7-((2R,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4,4-dimethyl-3,5,9,11-tetraoxa-tricyclo[6.2.1.02,6]undecane (129885-85-4)

Guidance literature:

With molecular sieve; triphenylmethyl perchlorate; In benzene; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1246/cl.1990.849

upstream raw materials:

3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl dimethylphosphinothioate

1,6-anhydro-3,4-O-isopropylidene-β-D-galactopyranose