[(Me(C₃HN₂)(Mes)CH₂)2CH]Rh(iodide)(acetonitrile)2⁽¹⁺⁾

Base Information

• Chemical Name: [(Me(C₃HN₂)(Mes)CH₂)2CH]Rh(iodide)(acetonitrile)2⁽¹⁺⁾
• CAS No.: 1338433-71-8
• Molecular Formula: C₃₃H₄₁IN₆Rh
• Molecular Weight: 751.539
• Mol file: 1338433-71-8.mol

Synonyms:

Chemical Property of [(Me(C₃HN₂)(Mes)CH₂)2CH]Rh(iodide)(acetonitrile)2⁽¹⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Me(C₃HN₂)(Mes)CH₂)2CH]Rh(iodide)(acetonitrile)2⁽¹⁺⁾

There total 2 articles about [(Me(C₃HN₂)(Mes)CH₂)2CH]Rh(iodide)(acetonitrile)2⁽¹⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(Me(C3H2N2)(Mes)CH2)2CH2]Br2 + rhodium(III)chloride (10049-07-7) + acetonitrile (75-05-8,26809-02-9) + potassium iodide (7681-11-0) → [(Me(C3HN2)(Mes)CH2)2CH]Rh(iodide)(acetonitrile)2(1+) (1338433-71-8,1338534-05-6)

Guidance literature:

With NaO₂CCH₃; air; In acetonitrile; mixing Rh compd., N compd., MeCN, NaOAc, KI, heating under reflux in air;

DOI:10.1039/c1dt11116g

Reference yield:

([((Me(C3HN2)(Mes)CH2)2CH)Rh]2(iodide)3)I (1338470-64-6) + acetonitrile (75-05-8,26809-02-9) → [(Me(C3HN2)(Mes)CH2)2CH]Rh(iodide)(acetonitrile)2(1+) (1338433-71-8,1338534-05-6)

Guidance literature:

In acetonitrile; dissolving Rh complex in MeCN; isolation as a mixture of isomers (1.2:1);

DOI:10.1039/c1dt11116g

Reference yield:

[(Me(C3HN2)(Mes)CH2)2CH]Rh(iodide)(acetonitrile)2(1+) (1338433-71-8,1338534-05-6) → ([((Me(C3HN2)(Mes)CH2)2CH)Rh]2(iodide)3)I (1338470-64-6)

Guidance literature:

In dichloromethane; dissolving Rh complex in CH2Cl2 at room temp.;

DOI:10.1039/c1dt11116g

upstream raw materials:

rhodium(III)chloride

acetonitrile

potassium iodide

([((Me(C₃HN₂)(Mes)CH₂)2CH)Rh]2(iodide)3)I

Downstream raw materials:

([((Me(C₃HN₂)(Mes)CH₂)2CH)Rh]2(iodide)3)I