Tributyl(cyanomethyl)phosphonium Chloride

Base Information

• Chemical Name: Tributyl(cyanomethyl)phosphonium Chloride
• CAS No.: 82358-61-0
• Molecular Formula: C₁₄H₂₉NP*Cl
• Molecular Weight: 277.818
• European Community (EC) Number: 679-652-9
• DSSTox Substance ID: DTXSID30469166
• NSC Number: 41943
• Mol file: 82358-61-0.mol

Synonyms:82358-61-0;Tributyl(cyanomethyl)phosphonium Chloride;(Cyanomethyl)tributylphosphonium Chloride;Cyanomethyltri-n-butylphosphonium chloride;tributyl(cyanomethyl)phosphanium chloride;Tributyl(cyanomethyl)phosphanium;chloride;MFCD00671508;C14H29ClNP;SCHEMBL5145658;DTXSID30469166;NSC41943;NSC-41943;AKOS015833117;SY043125;CS-0037541;W10650;EN300-7372770;A927994

Chemical Property of Tributyl(cyanomethyl)phosphonium Chloride

Chemical Property:

• Melting Point: 97°C
• PSA: 37.38000
• LogP: 1.93188
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: soluble in Methanol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 10
• Exact Mass: 277.1726146
• Heavy Atom Count: 17
• Complexity: 182

Purity/Quality:

98% min ^*data from raw suppliers

Tributyl(cyanomethyl)phosphonium Chloride ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

Useful:

• Canonical SMILES: CCCC[P+](CCCC)(CCCC)CC#N.[Cl-]

Technology Process of Tributyl(cyanomethyl)phosphonium Chloride

There total 1 articles about Tributyl(cyanomethyl)phosphonium Chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

tributylphosphine (998-40-3) + chloroacetonitrile (107-14-2) → (cyanomethyl)tributylphosphonium chloride (82358-61-0)

Guidance literature:

In nitromethane; at 20 ℃; for 16h;

DOI:10.1248/cpb.53.1508

upstream raw materials:

tributylphosphine

chloroacetonitrile

Refernces

• 1、 Sakamoto, Izumi,Nishii, Takeshi,Ozaki, Fumie,Kaku, Hiroto,Tanaka, Masami,Tsunoda, Tetsuto. "Preparation of (cyanomethylene)tributylphosphorane: A new mitsunobu-type reagent". . p. 1508 - 1509. Retrieved 2007/10/03.