tert-butoxy[(2,4,6-trimethylphenyl)(trimethylsilyl)amino]germane(II)

Base Information

• Chemical Name: tert-butoxy[(2,4,6-trimethylphenyl)(trimethylsilyl)amino]germane(II)
• CAS No.: 97241-53-7
• Molecular Formula: C₁₆H₂₉GeNOSi
• Molecular Weight: 352.088
• Mol file: 97241-53-7.mol

Synonyms:

Chemical Property of tert-butoxy[(2,4,6-trimethylphenyl)(trimethylsilyl)amino]germane(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butoxy[(2,4,6-trimethylphenyl)(trimethylsilyl)amino]germane(II)

There total 1 articles about tert-butoxy[(2,4,6-trimethylphenyl)(trimethylsilyl)amino]germane(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

germanium(II) chloride dioxane + N-(trimethylsilyl)-2,4,6-trimethylaniline (69563-04-8) → tert-butoxy[(2,4,6-trimethylphenyl)(trimethylsilyl)amino]germane(II) (97241-53-7) + bis{(2,4,6-trimethylphenyl)(trimethylsilyl)amino}germane(II) (97217-33-9)

Guidance literature:

With tert.-butyl lithium; In tetrahydrofuran; hexane; byproducts: LiCl, C4H8O2; dropwise addn. of t-BuLi/hexane to a soln. of the amine in hexane/THF at room temp.; refluxed for 6 h; addn. of GeCl2-dioxane at 0°C; stirred at 0°C for 1 h; refluxed for 6 h;; removal of solvent under reduced pressure; all volatiles were quickly distd. and sublimed under high vac. by heating at 270°C; fractional distn. of the the condensed mixt. under high vac.; elem. anal.;;

upstream raw materials:

N-(trimethylsilyl)-2,4,6-trimethylaniline