Technology Process of Silanamine, 1,1,1-trimethyl-N-(2,4,6-trimethylphenyl)-, germanium(2+)
salt
There total 2 articles about Silanamine, 1,1,1-trimethyl-N-(2,4,6-trimethylphenyl)-, germanium(2+)
salt which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyllithium;
In
tetrahydrofuran; hexane;
byproducts: LiCl, C4H8O2; dropwise addn. of 0.2 mol n-BuLi/hexane to a soln. of the amine (0.2 mol) in hexane/THF at room temp.; refluxed for 6 h; addn. of GeCl2-dioxane(0.1 mol) at 0°C; stirred at 0°C for 1 h; refluxed for 6 h;; removal of solvent under reduced pressure; all volatiles were quickly distd. and sublimed under high vac. by heating at 270°C; fractional distn. of the the condensed mixt. under high vac.; elem. anal.;;
- Guidance literature:
-
With
tert.-butyl lithium;
In
tetrahydrofuran; hexane;
byproducts: LiCl, C4H8O2; dropwise addn. of t-BuLi/hexane to a soln. of the amine in hexane/THF at room temp.; refluxed for 6 h; addn. of GeCl2-dioxane at 0°C; stirred at 0°C for 1 h; refluxed for 6 h;; removal of solvent under reduced pressure; all volatiles were quickly distd. and sublimed under high vac. by heating at 270°C; fractional distn. of the the condensed mixt. under high vac.; elem. anal.;;
- Guidance literature:
-
In
tetrahydrofuran;
byproducts: N2; equimolar amt. of arylazide in THF added dropwise to soln. of the diazagermylene in THF with stirring (ambient temp.), kept at 25°C for 2h; deep-red react. mixt. concd. (reduced pressure), crystn., filtered, dried (vac.);
DOI:10.1039/c39910001123
