PhC(SnMe₃)C(C₆H₄-p-OMe)(C₆H₄-p-F)

Base Information

• Chemical Name: PhC(SnMe₃)C(C₆H₄-p-OMe)(C₆H₄-p-F)
• CAS No.: 1240047-82-8
• Molecular Formula: C₂₄H₂₅FOSn
• Molecular Weight: 467.17
• Mol file: 1240047-82-8.mol

Synonyms:

Chemical Property of PhC(SnMe₃)C(C₆H₄-p-OMe)(C₆H₄-p-F)

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of PhC(SnMe₃)C(C₆H₄-p-OMe)(C₆H₄-p-F)

There total 1 articles about PhC(SnMe₃)C(C₆H₄-p-OMe)(C₆H₄-p-F) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(trimethylstannyl)lithium (17946-71-3) + para-iodoanisole (696-62-8) + (4-fluorophenyl)phenylacetylene (405-29-8) → PhC(SnMe3)C(C6H4-p-OMe)(C6H4-p-F) (1240047-82-8) + PhC(C6H4-p-OMe)C(SnMe3)(C6H4-p-F) (1240047-81-7)

Guidance literature:

With ZnCl₂; Pd₂(C₆H₅CHCHCOCHCHC₆H₅)3*CHCl₃; (C₆H₁₁)2PC₆H₄C₆H₃(OCH₃)2; In tetrahydrofuran; hexane; reaction of diphenylacetylene with 1.1 equiv. of tin compd. in hexane at0°C, treatment with 1.1 equiv. of ZnCl2 in 2:1 hexane/THF at 0.d egree.C, warming to room temp., addn. of anisyl iodide, palladium compd.and phosphine deriv. at room temp.;

DOI:10.1021/ja1059119

upstream raw materials:

(trimethylstannyl)lithium

para-iodoanisole

(4-fluorophenyl)phenylacetylene