trans-P,P-Re(NPh)I₂(PPh₃)(2-diisopropylphosphinophenolate)

Base Information

Chemical Name:trans-P,P-Re(NPh)I₂(PPh₃)(2-diisopropylphosphinophenolate)
CAS No.:288099-27-4
Molecular Formula:C₃₆H₃₈I₂NOP₂Re
Molecular Weight:1002.67
Hs Code.:

trans-P,P-Re(NPh)I<sub>2</sub>(PPh<sub>3</sub>)(2-diisopropylphosphinophenolate)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-P,P-Re(NPh)I₂(PPh₃)(2-diisopropylphosphinophenolate)

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Technology Process of trans-P,P-Re(NPh)I₂(PPh₃)(2-diisopropylphosphinophenolate)

There total 1 articles about trans-P,P-Re(NPh)I₂(PPh₃)(2-diisopropylphosphinophenolate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

: 288099-31-0
Re(NC₆H₅)I₃(P(C₆H₅)3)2

: 288099-29-6
(2-hydroxyphenyl)diisopropylphosphine

: 288099-27-4
trans-P,P-Re(NPh)I₂(PPh₃)(2-diisopropylphosphinophenolate)

: trans-P,P-Re(NPh)I(2-diisopropylphosphinophenolate)2

Guidance literature:: In toluene; under N2, in refluxing toluene, 47 h, phosphine:Re-complex molar ratio was 2:1, at 4:1 ratio bis-phosphine complex was formed with quant. yield; soln. was concd. in vac., solid was treated with Et2O, soln. was cooled,solid was filtered off, dried in vac., chromy., silica, mono- or bis-phosphine complexes were eluted with CHCl3 or Et2O, resp., recrystn. from Et2O at -20 °C, elem. anal.;
DOI:10.1016/S0277-5387(00)00360-0