288099-29-6Relevant academic research and scientific papers
2-Phosphanylphenolate Nickel Catalysts for the Polymerization of Ethylene
Heinicke, Joachim,Koehler, Martin,Peulecke, Normen,He, Mengzhen,Kindermann, Markus K.,Keim, Wilhelm,Fink, Gerhard
, p. 6093 - 6107 (2007/10/03)
The previously unknown methallylnickel 2-diorganophosphanylphenolates (R=Ph, cHex) were synthesized and found to catalyze the polymerization of ethylene. To explore the potential for ligand-tuning, a variety of P-alkyl- and P-phenyl-2-phosphanylphenols wa
New chiral phosphine-phosphites: A convenient synthesis based on the demethylation of o-anisyl phosphines and application in highly enantioselective catalytic hydrogenations
Suarez, Andres,Pizzano, Antonio
, p. 2501 - 2504 (2007/10/03)
An easy demethylation of o-anisyl phosphines provides a convenient access to a series of new chiral phosphine-phosphites. The screening of these derivatives as ligands in rhodium-catalyzed asymmetric hydrogenation of dimethyl itaconate has shown a profoun
