mer-[(Ph2PC6H4CH2OCH2C5H4N-κ(3)P,N)Rh(cyclooctadiene)]PF6

Base Information

• Chemical Name: mer-[(Ph2PC6H4CH2OCH2C5H4N-κ(3)P,N)Rh(cyclooctadiene)]PF6
• CAS No.: 920742-72-9
• Molecular Formula: C₃₃H₃₄NOPRh*F₆P
• Molecular Weight: 739.482
• Mol file: 920742-72-9.mol

Synonyms:

Chemical Property of mer-[(Ph2PC6H4CH2OCH2C5H4N-κ(3)P,N)Rh(cyclooctadiene)]PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mer-[(Ph2PC6H4CH2OCH2C5H4N-κ(3)P,N)Rh(cyclooctadiene)]PF6

There total 1 articles about mer-[(Ph2PC6H4CH2OCH2C5H4N-κ(3)P,N)Rh(cyclooctadiene)]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro(1,5-cyclooctadiene)rhodium(I) dimer + silver(I) hexafluorophosphate (26042-63-7) + o-Ph2PC6H4CH2OCH2C5H4N-2 (146583-33-7) → mer-[(Ph2PC6H4CH2OCH2C5H4N-κ(3)P,N)Rh(cyclooctadiene)]PF6 (920742-72-9)

Guidance literature:

In ethanol; (Ar); std. Schlenk technique; soln. of AgPF6 in EtOH added dropwise to stirred suspn. of Rh complex (1 equiv.) in EtOH; stirred at room temp. for 90 min; filtered; filtrate added to soln. of P-N ligand (2 equiv.) in EtOH; stirred at room temp. for 5 h; solvent removed (vac.); washed (EtOH); recrystd. (CH2Cl2/ether); elem. anal.;

DOI:10.1021/om060405d

upstream raw materials:

silver(I) hexafluorophosphate

o-Ph₂PC₆H₄CH₂OCH₂C₅H₄N-2