[(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl]

Base Information

• Chemical Name: [(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl]
• CAS No.: 1192144-29-8
• Molecular Formula: C₃H₉AlCl*C₃₁H₃₉CoN₃
• Molecular Weight: 620.203
• Mol file: 1192144-29-8.mol

Synonyms:

Chemical Property of [(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl]

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of [(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl]

There total 1 articles about [(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-bis[1-(2-tertbutylphenylimino)ethyl]pyridine cobalt(II) dichloride (204203-12-3) + ethene (74-85-1) + trimethylaluminum (75-24-1) → [(NC5H3(C(Me)NC6H4-t-Bu)2)Co(I)(η-ethylene)][AlMe3Cl] (1192144-29-8)

Guidance literature:

In ⁽²⁾H₈-toluene; using sealed high vac. systems; in NMR tube; Co complex cooled in liq. N2 (77 K); toluene-d8 and AlMe3 added; ethylene introduced; reacted at -30°C; not isolated; monitored by (1)H NMR spectra;

DOI:10.1021/om900490b

upstream raw materials:

2,6-bis[1-(2-tertbutylphenylimino)ethyl]pyridine cobalt(II) dichloride

ethene

trimethylaluminum