(CH₃C₆H₄S)2CSO

Base Information

• Chemical Name: (CH₃C₆H₄S)2CSO
• CAS No.: 77280-37-6
• Molecular Formula: C₁₅H₁₄OS₃
• Molecular Weight: 306.474
• Mol file: 77280-37-6.mol

Synonyms:

Chemical Property of (CH₃C₆H₄S)2CSO

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (CH₃C₆H₄S)2CSO

There total 1 articles about (CH₃C₆H₄S)2CSO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[RhCl(P(C6H11)3)((CH3C6H4S)2CSO)] → [RhCl(CO)2(P(C6H11)3)] + [RhCl(CO)(P(C6H11)3)2] (26534-14-5,17966-79-9) + trans-((C6H11)3P)2Rh(CO)Cl (17966-79-9,26534-14-5) + (CH3C6H4S)2CSO (77280-37-6)

Guidance literature:

With carbon monoxide; In chloroform-d1; bubbling CO through CDCl3 soln. of Rh complex; not isolated; detected by NMR;

DOI:10.1039/DT9820000397

Reference yield: 40.0%

bis(cycloocta-1,5-diene)platinum(0) + ethene (74-85-1) + (CH3C6H4S)2CSO (77280-37-6) + tricyclohexylphosphine (2622-14-2) → Pt(CH3C6H4S)2CSO(P(C6H11)3)2

Guidance literature:

In toluene; pentane; stirred for 1.5 h at -20°C; ppt. filtered, washed with n-pentane, dried in vac.; elem. anal.;

DOI:10.1039/DT9810001342

Reference yield:

tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + (CH3C6H4S)2CSO (77280-37-6) → [Pd(P(C6H5)3)2((CH3C6H4S)2CSO)]

Guidance literature:

In benzene; stirred under N2 at room temp. for 2 h; solvent evapd., pentane added, stirred for 18 h, ppt. filtered, dried in vac., elem. anal.;

DOI:10.1016/S0022-328X(00)89022-1