[(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))](2+)

Base Information

• Chemical Name: [(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))](2+)
• CAS No.: 1350626-43-5
• Molecular Formula: C₂₅H₃₂N₃ORuS
• Molecular Weight: 523.685
• Mol file: 1350626-43-5.mol

Synonyms:

Chemical Property of [(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))](2+)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))](2+)

There total 3 articles about [(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))](2+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

GLUTATHIONE (70-18-8) + [(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))]PF6 (1350626-35-5) + dihydrogen peroxide (7722-84-1) → [(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))](2+) (1350626-43-5) + [(η6-p-cymene)Ru(ethylenediamine)(SO2C6H4CONHC6H5)](1+) (1350626-42-4) + [((η6-p-cymene)Ru)2(glutathione(-1H))3](1+)

Guidance literature:

With catalase; In further solvent(s); byproducts: HSC6H4CONHC6H5, C7H4SN(O)C6H5, C7H4SN(O)2C6H5; Ru complex reacted with H2O2 in phosphate buffer at pH 7.4 for 24 h at 298 K, catalase added, ligand added, incubated at 298 K for 72 h; not isolated, detected by MS;

DOI:10.1039/c1dt11189b

Reference yield:

[(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))]PF6 (1350626-35-5) + dihydrogen peroxide (7722-84-1) → [(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))](2+) (1350626-43-5) + [(η6-p-cymene)Ru(ethylenediamine)(SO2C6H4CONHC6H5)](1+) (1350626-42-4)

Guidance literature:

In further solvent(s); byproducts: C7H4SN(O)C6H5, C7H4SN(O)2C6H5; incubated at pH 7.4 in phosphate buffer contg. MeCN at 298 K; not isolated, detected by MS;

DOI:10.1039/c1dt11189b

Reference yield:

[(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))]PF6 (1350626-35-5) + dihydrogen peroxide (7722-84-1) → [(η6-p-cymene)Ru(H2O)2(2-mercaptobenzanilide(-1H))](1+) (1350626-41-3) + [(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))](2+) (1350626-43-5) + [(η6-p-cymene)Ru(ethylenediamine)(SO2C6H4CONHC6H5)](1+) (1350626-42-4)

Guidance literature:

In further solvent(s); byproducts: C7H4SN(O)C6H5; at pH 5.3 in phosphate buffer at 298 K; not isolated, detected by MS;

DOI:10.1039/c1dt11189b

upstream raw materials:

[(η6-p-cymene)Ru(ethylenediamine)(2-mercaptobenzanilide(-1H))]PF6

dihydrogen peroxide

GLUTATHIONE